Trouble with Gibbs Free Energy & Equilibrium Constant Calc.

[Electric to be]

Hello. A known equation that is useful for calculating equilbrium constants is:

ΔG° = -RT * ln(K)

This is all well and good. Given a standard gibbs free energy of reaction for some given reaction, the equilibrium constant for the reaction can be found.

My trouble is in which ΔG° to use. For example given the following reaction:

N₂ + 3H₂ ↔ 2NH₃ ΔG° = -33.0 KJ

The ΔG° can be calculated by taking the difference of Gibbs Free Energy of formation of each reactant and product, multiplying by the respective stoichiometric constant, and taking the difference.

Then, when I plug in this value for ΔG° I can find a unique equilibrium constant to describe this reaction.My trouble is the following. What's to stop me from halving all constants of the equation and getting this? :

1/2N₂ + 3/2H₂ ↔ 1NH₃ ΔG° = -16.5 KJ

Now, per "mole" of the equation (which is 1/2 N₂, 3/2H₂ and 1NH₃), there is one half of the original Gibb's free energy release. However, this still represents a standard gibbs free energy, by following the same process as before of taking the difference between products and reactants. However, I will certainly get a different value of K. The equilibrium constant should remain the same though, should it not? It shouldn't matter what multiple of the equation have. This is my confusion.As a side question, should ΔG° describing this type of reaction have units of KJ/mol? I know in the Gibbs free energy of formation it is. However, generally when I've seen free energy of reaction written it has only had units of J or KJ, since the moles were multiplied through in the process of finding ΔG°. If it does have KJ/mol units, would 1 "mol" of reaction essentially be 1 mol * each stoichiometric constant of the products and reactants for a given equation?

 

[Borek]

The equilibrium constant should remain the same though, should it not?

$$\frac{[NH_3]^2}{[N_2][H_2]^3} = \sqrt{ \frac{[NH_3]}{[N_2]^{\frac 1 2}[H_2]^{\frac 3 2}}}$$

 

[James Pelezo]

Use the ΔG^o for the reaction of interest. Changing the coefficients of the reaction does change the reaction kinetics and the equilibrium constant. By dividing the Haber-Bosch equation (N₂(g) + 3H₂(g) => 2NH₃(g)) by 2 effectively doubles the equilibrium constant value of the reaction. The equation which yields 2 moles NH₃(g) has a K_STD = 1.64 X 10^-6, but dividing by 2 => K_NON-STD = 1.28 X 10^-3.

[K(2NH₃)]^½ = [([NH₃]²/[N₂][H₂]³)]^½ = [K(NH₃)] = [NH₃]^½/[N₂]^½[H₂]^3/2]

 

[James Pelezo]

Correction... Dividing by 2 => increases K-value by ~780x. SBT