Understanding Electric Dipole Transitions: Problem #2

In summary, problem #2 in the attached PDF concerns the selection rules for electric dipole allowed transitions, assuming Russell-Saunders coupling. The transition in question is 4f2(^3F_2)->4f3(^3H_4), and the applicable selection rules are dS=0, dL=+1, dJ=-1, dMJ=0, dML=+1, dMS=0, with the Laporte selection rule for parity not being applicable.
  • #1
jajay504
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0

Homework Statement



Attached PDF. Problem # 2.

Homework Equations


Used parity selection rule, Assumed Russell-Saunders Coupling


The Attempt at a Solution


I only understand the electric dipole allowed transitions from reading. I don't actually understand how they work. For the electron undergoing the transition, dl= +/-1. The d represents delta. For the atom as a whole, the following selection rules apply:
dS=0, dL=0, +/- 1
dJ=0, +/-1 except 0<->0
dMJ= 0, +/-1 except 0<-> for dJ=0
dML=0, +/- 1
dMS=0, +/-1
Laporte selection rule on parity: u <-> g g<-x->g u<-x->u
 
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  • #2
For the transition in question, 4f2(^3F_2)->4f3(^3H_4), the following selection rules are applicable:dS=0, dL=+1, dJ=-1, dMJ=0, dML=+1, dMS=0. The Laporte selection rule for parity is not applicable as the initial and final state have the same parity.
 

Related to Understanding Electric Dipole Transitions: Problem #2

1. What is an electric dipole transition?

An electric dipole transition is a change in the energy state of an atom or molecule, which results in the emission or absorption of electromagnetic radiation.

2. What is the significance of electric dipole transitions?

Electric dipole transitions allow us to study the electronic structure of atoms and molecules, and they play a crucial role in various fields such as spectroscopy, quantum mechanics, and astrophysics.

3. How is electric dipole transition probability calculated?

The electric dipole transition probability is calculated using the transition moment, which is the product of the dipole moment and the wavefunction of the initial and final states.

4. What is the selection rule for electric dipole transitions?

The selection rule for electric dipole transitions states that the initial and final states must have a change in their parity, which is determined by their wavefunctions, in order for a transition to be allowed.

5. How can electric dipole transitions be experimentally observed?

Electric dipole transitions can be observed through various experimental techniques such as absorption spectroscopy, emission spectroscopy, and Raman spectroscopy, which measure the absorption and emission of electromagnetic radiation by atoms or molecules.

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