Values of the agular momentum quantum number

In summary, the principle quantum number limits the values of the angular momentum quantum number, l, to be less than or equal to n-1. This is derived from the Schrodinger equation when solving the Hydrogen atom. The approach involves separating the variables and solving the Colatitude and Azimuthal equations. The restriction for l only applies to hydrogenic systems.
  • #1
fkliment2000
8
0
Hello!

Why is it the case, that the principle quantum number limits the values of the angular momentum quantum number like

l <= n-1

How is it possible to derive this?


Thank you for your answers.
 
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  • #2
It falls out the the Schrodinger equation (SE) when solving the Hydrogen atom. On approach to solving the SE is to separate the variables into different equations. In order to solve the SE, we separate the radial part and set it equal to a constant. This yields what is known as the Colatitude equation. We then separate the Azimuthal Equation (which coincidentaly is the easiest to solve) and solve. This gives the value of the constant in the Colatitude equation and the azimuthal quantum number. We then solve the Colatitude equation using ploynomial expansion and obtain solutions of the form [itex]C = l(l+1)[/itex] and the solution only exists if l = 0,1,2,3,...,n-1

More information is available at http://hyperphysics.phy-astr.gsu.edu/hbase/quantum/hydsch.html#c2
 
  • #3
Thanks very much! :smile:
 
  • #4
Also, note that this restriction only holds for hydrogenic systems.
 

Related to Values of the agular momentum quantum number

What is the angular momentum quantum number?

The angular momentum quantum number, denoted by the letter l, is a quantum number that represents the shape of an electron's orbital in an atom. It determines the subshell in which the electron is located and the number of angular nodes present in the orbital.

What are the possible values of the angular momentum quantum number?

The possible values of the angular momentum quantum number range from 0 to n-1, where n is the principal quantum number. This means that for a given value of n, the possible values of l are 0, 1, 2, 3... up to n-1.

What is the relationship between the angular momentum quantum number and the shape of an orbital?

The value of the angular momentum quantum number determines the shape of an orbital. For example, if l = 0, the orbital is spherically shaped, while l = 1 corresponds to a dumbbell-shaped orbital. The higher the value of l, the more complex the shape of the orbital becomes.

How does the angular momentum quantum number affect the energy of an electron?

The energy of an electron is determined by its principal quantum number (n) and its angular momentum quantum number (l). As the value of l increases, the energy of the electron also increases. This is because higher values of l correspond to more complex and higher energy orbital shapes.

What is the significance of the angular momentum quantum number in the periodic table?

The angular momentum quantum number is important in understanding the organization of the periodic table. The values of l determine the order in which the subshells are filled with electrons, which in turn affects the chemical and physical properties of elements. For example, elements in the same group of the periodic table have the same outermost subshell, which is determined by the value of l.

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