What gas is produced when copper is added to diluted HCl?

In summary, copper pennies were placed into diluted HCl and bubbles were formed on the pennies for the first 2 days. The gas from the bubbles could be hydrogen gas as a result of a reaction between the HCl and any oils or dirt on the pennies. This gas may cause discomfort to the eyes. It is also possible that some HCl gas may come out of solution during the reaction. Another possibility is that the bubbles are carbon dioxide from the formation of copper carbonate due to corrosion.
  • #1
SDTK
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Copper pennies were placed into HCl which had been diluted with an unknown quantity of water.

The pennies look cleaner, ... remain un-corroded (as expected). There is a slight bit of gas being produced , with no smell, but can cause discomfort to eyes. Bubbles formed on the pennies for the first 2 days.

-- What is the gas?

-- Could it be a product of reaction with the HCl and any oils, "dirt" that was on the pennies?
 
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  • #2
If it causes discomfort to the eyes, it is not hydrogen. That only leaves one possibility...
 
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  • #3
Some HCl may come out from solution as HCl gas which may irritate your eyes. The gas from bubbles you saw happening might be Hydrogen gas, H2.

Cu + 2H+ ---------> Cu+2 + H2
 
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  • #4
Equilibrium concentration of Cu2+ in the presence of non-oxidizing acid is in the 10-11 M range, I don't think that's enough for the bubble formation.
 
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  • #5
symbolipoint said:
Some HCl may come out from solution as HCl gas which may irritate your eyes. The gas from bubbles you saw happening might be Hydrogen gas, H2.

Cu + 2H+ ---------> Cu+2 + H2
thank you
 
  • #6
Borek said:
Equilibrium concentration of Cu2+ in the presence of non-oxidizing acid is in the 10-11 M range, I don't think that's enough for the bubble formation.
thank you
 
  • #7
It could be carbon dioxide if some copper carbonate had formed on the coins as a result of corrosion.
 

1. What is the reaction between copper and diluted HCl?

The reaction between copper and diluted HCl is a single replacement reaction, where the copper metal replaces the hydrogen in the acid to form copper chloride and hydrogen gas.

2. What is the chemical equation for the reaction between copper and diluted HCl?

The chemical equation for the reaction between copper and diluted HCl is Cu + 2HCl → CuCl2 + H2.

3. Why is hydrogen gas produced in this reaction?

Hydrogen gas is produced because copper is more reactive than hydrogen, so it displaces the hydrogen in the acid to form a new compound and release the hydrogen gas.

4. How does the concentration of HCl affect the amount of gas produced?

The concentration of HCl affects the amount of gas produced because a higher concentration of acid means there are more reactant particles available for the reaction, resulting in a larger amount of gas produced.

5. Is the reaction between copper and diluted HCl exothermic or endothermic?

The reaction between copper and diluted HCl is exothermic, meaning it releases heat energy. This can be observed through the production of hydrogen gas and the increase in temperature of the reaction mixture.

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