Okay, process 3 also isn't possible due to the delta having spin 3/2, the pion having spin 0 and the neutron having spin 1/2 so this is also impossible due to spin not being conserved?
Process 4
Baryon Number 0 + 1 -> 1 + 0, conserved
Spin 0 + 1/2 -> 1/2 + 0, conserved
So process 4 is...