Why Does Electron Affinity Have Different Values and Conventions?

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Electron affinity (EA) is defined as the energy released when an atom gains an electron, but conventions differ between physicists and chemists. Physicists often use a negative sign convention for EA, while chemists report all values as positive. This discrepancy can lead to confusion, particularly when comparing sources like Wikipedia and HyperPhysics, which present differing conventions. The process of detaching an electron from a negatively charged ion is described as the reverse of gaining an electron, adding to the complexity. Understanding these conventions is crucial for accurate interpretation of electron affinity values in various contexts.
philip041
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I have been looking at websites on electron affinity. My notes report it as 'energy released when an atom gains an electron. Wikipedia http://en.wikipedia.org/wiki/Electron_affinity says the amount of energy released when detaching an electron from a singly charged negative ion,[1] i.e., the energy change for the process

X- → X + e−

This seems the reverse? Also on that same Wikipedia page it says you can't get negative elctron affinity values yet on good old hyperphysics http://hyperphysics.phy-astr.gsu.edu/Hbase/chemical/eleaff.html it uses a negative convention. I thought this was a modern site?

Can someone clear this up? Cheers!
 
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