How Do Monoclinic to Triclinic Lattice Transformations Occur?

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The discussion focuses on the transformation of monoclinic crystal structures to triclinic ones, specifically detailing the relationships between their lattice parameters. The formulas provided indicate how the parameters for the triclinic structure (T) can be derived from those of the monoclinic structure (M). The source of these formulas is identified as 'PRL 99, 247211 (2007)', which discusses magnetoelastic coupling and symmetry breaking in a specific antiferromagnet. Participants suggest using 3D modeling software, such as AutoCAD, to visualize and verify the transformation numerically. Further inquiries about the derivation of the formulas and additional literature sources are welcomed.
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According to the literature, when monoclinic crystal structure transforms to triclinic, the following formulaes, regarding their lattice parameters are valid:

a(T) = 1/2 a(M) - 1/2 b(M)
b(T) = 1/2 a(M) + 1/2 b(M)
c(T) = c(M)

Where T and M stand for Triclinic and Monoclinic, respectively.

Could anyone please inform how do these formulaes come up or any literature source to search further?

Thanks a lot!
 
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This looks like it might be a transformation from a face-centered monoclinic to a triclinic. One way to check would be to contruct the lattice on some 3D modeling software (like AutoCAD), and perform the transformations numerically.

What is your source for the relations?
 
The source is 'PRL 99, 247211 (2007)', 'Magnetoelastic Coupling and Symmetry Breaking
in the Frustrated Antiferromagnet -NaMnO2'. The formulas are presented on the last page, page 4, of this paper.

Any response is kindly welcome.


Gokul43201 said:
This looks like it might be a transformation from a face-centered monoclinic to a triclinic. One way to check would be to contruct the lattice on some 3D modeling software (like AutoCAD), and perform the transformations numerically.

What is your source for the relations?
 

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