Statisical mechanics Definition and 26 Threads

The Gibbs sum is given by $$Z=\sum[\lambda \exp(-\varepsilon/\tau)]^N$$ where ##\lambda\equiv\exp(\mu/\tau)##. Since we are assuming ##\mu>\varepsilon##, we take only the last term of the sum because all others can be neglected. thus $$Z\approx[\lambda \exp(-\varepsilon/\tau)]^N$$ Now...

So to get the partition function I do the integral ##\int \alpha E^{3} e^{(B_{0}-B)E} dE##, which substituting in ##/Delta B = B_{0} - B## is ##Z = \frac{ \alpha E^{3} e^{\Delta B E}}{\Delta B} - \frac{3 \alpha E^{2} e^{\Delta B}}{\Delta B^{2}} + \frac{6 \alpha E e^{\Delta B E}}{\Delta B ^{3}} -...

While reading a similar and deservedly closed post a contradiction came to my mind. The supposed contradiction is related to Statistical Physics where my understanding is only conceptual so correct me where I might be wrong. I remember reading that lightweight gasses can escape Earth's...

Hi guys, Can you give me some feedback on whether my calculation is correct? I applied the formula below (Boltzmann Distribution) but I didn‘t know what to use for the variable z. I don‘t even know if I used the correct equation. Can you help me further? The task is: Consider a system of...

##Z = \sum_{-i}^{i} = e^{-E_n \beta}## ##Z = \sum_{0}^j e^{nh\beta} + \sum_{0}^j e^{-nh\beta}## Those sums are 2 finites geometric series ##Z = \frac{1- e^{h\beta(i+1)}}{1-e^{h\beta}} + \frac{1-e^{-h\beta(i+1)}}{1-e^{-h\beta}}## I don't think this is ring since from that I can't get 2 sinh...

what is the reason for that the energy hypersurfaces in a phase space, which belong to systems with constant energy are closed? ( see picture )

So the Langevin equation of Brownian motion is a stochastic differential equation defined as $$m {d \textbf{v} \over{dt} } = - \lambda \textbf{v} + \eta(t)$$ where the noise function eta has correlation function $$\langle \eta_i(t) \eta_j(t') \rangle=2 \lambda k_B T \delta_{ij} \delta(t -...

Attempt at a solution: \begin{aligned}Z=\sum ^{N}_{r=0}C\left( N,r\right) e^{-\beta \left[ -NJ+2rJ\right] }\\ \Rightarrow Z=e^{\beta NJ}\sum ^{N}_{r=0}C\left( N,r\right) e^{-2\beta rJ}\end{aligned} Let ##e^{-2\beta J}=x##. Then ##e^{-2\beta rJ}=x^{r}##. \begin{aligned}\therefore Z=e^{\beta...

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Is Non-equilibrium statistical physics and complex systems a good area of study to go into? Is it a well respected field? Thank you

In a statistical mechanics book, I learned about the degenerate pressure of a Fermi gas under the non-relativistic regime. By studying the low-temperature limit (T=0), we got degenerate pressure is ##\propto n^{5/3}## (n is the density). And then I was told that in astrophysical objects, the...

In the discussion of the pressure in macrocanonical ensemble, I found in textbook that: ##dW = \bar p dV## (##dW## is in fact d_bar W, yet I can't type the bar) The derivation goes like: ##\bar p = \frac{1}{Z} \sum_{r} e^{-\beta E_r} (-\frac{\partial E_r}{\partial V}) = ... = \frac{1}{\beta}...

In addition to the homework statement and considering only the case where ##U= constant## and ##N = large## : Can we also consider the definition of chemical potential ##\mu## and temperature ##T## as in equations ##(1)## and ##(2)##, and use them in the grand partition function? More...

Attempt at a Solution: Heat Absorbed By The System By the first law of thermodynamics, dU = dQ + dW The system is of fixed volume and therefore mechanically isolated. dW = 0 Therefore dQ = dU The change of energy of the system equals the change of energy of the gas plus the change of energy...

As everyone knows that we can go from Langevin equation to Fokker-Planck equation which gives the evolution of probability density function. But what I don't understand is what is exactly the main difference between them as long as they are both give the variance (which then we can for example...

In these lecture notes about statistical mechanics, page ##10##, we can see the graph below. It represents the distribution (probability density function) of the kinetic energy ##E## (a random variable) of all the gas particles (i.e., ##E=\sum_{i}^{N} E_{i}##, where ##E_{i}## (also a random...

For a system of interacting particles, is it possible to define single-particle phase spaces? If not, why?

assume i have a gass made from N identical particles in a box and i want to calculate the probability for k out of N particles to be in the left side of the box. the problem is ,that if we treat the N particles as identical , each state in which exacly k of the N particles are in the left side...

Hello, The relationship between entropy ##S##, the total number of particles ##N##, the total energy ##U(β)##, the partition function ##Z(β## and a yet to be defined constant ##β## is: $$S(\beta)=k_BN \cdot \ln(Z(\beta)) - \beta k_B \cdot U(\beta)$$ Which leads to: $$\frac{dS}{d\beta} =...

Data = np.array([-1.61032636, -1.23577245, -0.50587484, -0.28348457, -0.18748945, 0.4537447, 1.2338455, 2.13535718]) print("Data is: ", Data) print(Data.shape) n,bins,patches = plt.hist(Data,bins=4) print("n: ",n) print("bins: ",bins) plt.savefig("./DOS")

For my own understanding, I am trying to computationally solve a simple spinless fermionic Hamiltonian in Quantum Canonical Ensemble formalism . The Hamiltonian is written in the second quantization as $$H = \sum_{i=1}^L c_{i+1}^\dagger c_i + h.c.$$ In the canonical formalism, the density...

This is the text from Reif Statistical mechanics. In the screenshot he changes the summation to integral(Eq. 1.5.17) by saying that they are approximately continuous values. However,I don't see how. Can anyone justify this change?

Chemical potential is defined as the change in energy due to change in the number of particles in a system. Let we have a system which is defined by the following Hamiltonian: $$H = -t \sum_i^L c_i^\dagger c_{i+1} + V\sum_i^L n_i n_{i+1} -\mu \sum_i^L n_i$$ where ##c^\dagger (c)## are creation...

Salutations, I'm starting in statistical mechanics and reviewing some related studying cases I would like to understand what occurs in small systems with normal modes of vibration, for example, a small system that has 2 normal modes of vibration, with natural frequencies $$\omega_1$$ and...

Hi, guys I have posted this question on StackExchange, but no one seems to care answer. Because I don't think this is a simple textbook question, I start my thread here: I know this is a big question. But as a graduate student, my research is somehow related to nonequilibrium...

Title says it all really, I'm a second year undergraduate from oxford, and currently the textbook I've been using for stat. mech. is "Concepts in Thermal Physics", which was wirtten by my lecturer. I'd like (ideally) something a bit longer to work through suring the holidays, that would provide...