Double refraction, or birefringence, occurs in anisotropic materials where the refractive index varies along different axes, leading to the splitting of light into two beams with different velocities. This phenomenon is particularly evident in crystals like calcite, where unpolarized light entering the medium is divided into two polarized components that are refracted at different angles. The mechanism involves the polarization of molecules in response to an electric field, which affects how light propagates through the material. The discussion also touches on the role of the electric field in polarization, while noting that the magnetic field is typically not considered in this context. Additionally, questions arise regarding diffraction patterns in single slit experiments, specifically whether light passing through the center of a small slit will diffract and how this relates to classical and quantum interpretations.