A bead on a frictionless hoop experiences vertical acceleration at specific angles, determined by the conditions of forces acting on it. The critical points where the bead's acceleration is vertical occur when the normal force is zero, leading to the angles φ=0, cos⁻¹(2/3), π, and 2π-cos⁻¹(2/3). At these points, the acceleration is equal to g downwards, except at φ=0 where it is zero, and at φ=π where the net force results in a downward acceleration of 4g. The normal force changes direction at these angles, indicating a transition in the forces acting on the bead. Understanding these dynamics is essential for solving the problem accurately.