Allowed combinations of remaining quantum numbers when n = 3

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SUMMARY

The discussion focuses on the allowed combinations of quantum numbers for an atom with a principal quantum number n = 3 and angular momentum quantum number l = 2. The relevant quantum numbers are m (magnetic quantum number) and ms (spin quantum number). For l = 2, m can take values from -2 to +2, resulting in five possible values. Each electron can have a spin of either +1/2 or -1/2, leading to a total of 10 allowed combinations of m and ms, thus accommodating 10 electrons in the n = 3, l = 2 closed subshell.

PREREQUISITES
  • Understanding of quantum numbers: principal quantum number (n), angular momentum quantum number (l), magnetic quantum number (m), and spin quantum number (ms)
  • Familiarity with the concept of closed subshells in atomic structure
  • Knowledge of eigenvalues related to quantum operators, specifically \hat{L}z and \hat{S}z
  • Basic principles of electron spin and its implications in quantum mechanics
NEXT STEPS
  • Study the implications of quantum numbers in atomic structure and electron configurations
  • Learn about the Pauli exclusion principle and its effect on electron arrangements
  • Explore the significance of eigenvalues in quantum mechanics, particularly in relation to angular momentum
  • Investigate the role of closed subshells in chemical bonding and periodic trends
USEFUL FOR

Students of quantum mechanics, physicists, and chemists interested in atomic structure and electron configurations, particularly those studying the behavior of electrons in closed subshells.

Dixanadu
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Homework Statement


Hey everyone

I couldn't really fit a good description into the title. Basically here's what it is.

Consider an atom in which all the states with principal quantum number n = 3 and angular momentum quantum number l = 2 are occupied by electrons (this is called a closed subshell). List the allowed combinations of the remaining quantum numbers m,m_{s} which are related to the eigenvalues of \hat{L}_{z},S_{z}. Hence, how many electrons are in the n = 3, l = 2 closed subshell?


Homework Equations



Dont know of any

The Attempt at a Solution



I don't have a clue...need some help T_T
 
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What's the spin of an electron? That determines the allowed values for ms. What's the thing that tells you what values m can take?
 
Spin of an electron is either +1/2 or -1/2...that's m_{s} right? as far as m goes, is that the one that ranges from -l to +l...so it has 2l+1 values right? I just don't get what all this has to do with the eigenvalues of \hat{L} and S_{z}...
 
So m is the eigenvalue corresponding to operator \hat{L}_z, and ms corresponds to \hat{S}_z.

You basically got it, now you just need to figure out which values can m and ms take together, and how many combinations there are.
 
for m = 1/2:
m = -2, -1, 0, 1, 2

for m = -1/2
m= -2, -1, 0, 1, 2

So total is 10 electrons...?
 
Yap that looks correct
 

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