Atomic Structure- Energy diff between levels

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Homework Help Overview

The discussion revolves around calculating the energy difference between adjacent vibrational levels in the NaCl molecule, considering parameters such as atomic weights, internuclear separation, and the spring constant for vibrations.

Discussion Character

  • Exploratory, Assumption checking

Approaches and Questions Raised

  • The original poster attempts to calculate the reduced mass and subsequently the energy using the spring constant and angular frequency. Some participants question the units used for atomic weights and whether they are in kilograms, while others suggest verifying the definition of "atomic weight" to ensure correct mass calculations.

Discussion Status

The discussion is ongoing, with participants providing guidance on checking units and definitions. There is a focus on clarifying assumptions regarding the units of mass and the interpretation of atomic weight.

Contextual Notes

There is a lack of clarity regarding the units of atomic weights and how they should be converted to mass in kilograms for the calculations. Additionally, the original poster notes that the problem does not specify units, which has led to confusion.

rxy152
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Homework Statement


Consider the NaCl molecule, in which the atomic weights of Na and Cl are 23 and 37, respectively. The internuclear separation is 0.236 nm, and the ”spring constant” for vibrations is k = Mred ω^2 = 1 × 10^9 J/m^2 . Calculate the energy difference between adjacent vibrational levels. The value of h-bar is 1.055 × 10^−34 J · s. Answer in units of eV

Homework Equations

The Attempt at a Solution


I tried using reduced mass where m(red) = 23*37 / (23+37)= 14.18

Then plugged m(red) in the equation k = Mred ω^2 where i solved for ω = 8396

With ω, I used E=hbar * ω to get E = 8.8548E-31 J

= 5.527E-12 eV, which is wrong.

Plz Help!
 
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Check your units. Are the masses of Na and Cl in kg?
 
phyzguy said:
Check your units. Are the masses of Na and Cl in kg?

It doesn't state the units, which i thought was weird.

Here are some constants provided -
The value of h bar is 1.05457 × 10^−34 J · s ; the speed of light is 2.99799 × 10^8 m/s ; the value of h is 6.62607 × 10^−34 J · s ; the Rydberg constant for hydrogen is 1.09735 × 10^7 m −1 ; the Bohr radius is 5.29177 × 10^−11 m ; and the ground state energy for hydrogen 13.6057 eV .
 
rxy152 said:
It doesn't state the units, which i thought was weird.

You need to look up what "atomic weight" means, and how to calculate the mass of an atom (in kg) given its atomic weight.
 

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