Average shear rate of of particle sureface

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Homework Help Overview

The discussion revolves around calculating the average shear rate at the surface of 100 nm particles in a viscous solvent, given the diffusion coefficient and other parameters. The context includes fluid dynamics and particle motion in a viscous medium.

Discussion Character

  • Exploratory, Assumption checking, Problem interpretation

Approaches and Questions Raised

  • Participants discuss the applicability of equations related to diffusion and shear rate, questioning whether certain assumptions, such as the Peclet number being equal to one, are valid. There is also exploration of the relationship between particle velocity and shear rate, with references to different methods of calculating these values.

Discussion Status

Participants are actively engaging with the problem, sharing calculations and questioning the validity of their results. Some guidance has been offered regarding the definitions of shear rate and the equations relevant to the situation, but no consensus has been reached on the correct approach or final values.

Contextual Notes

There is uncertainty regarding the completeness of the problem statement and the definitions of terms such as shear rate in the context of the discussion. Participants are also navigating through different interpretations of the equations involved.

hizen_14
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Homework Statement


Diffusion coefficient (D) of 100 nm particles ( density = 1050 kg/m3) in a viscous solvent at 25 C is 2.2 x 10-13 m3/s

What is the average shear rate at the particle surface?

Homework Equations



D = kT/ 6πηa (1)
where k is Boltzmann constant, T = temperature, ηsusp = viscosity and a = radius

Pe = a2γ /D (2)

where γ = shear rate

The Attempt at a Solution


Assumed particles are in water

To find shear rate of particle surface I am not too sure that eq2 is the right equation to use or not. Can we assume that Pe = 1 ??

Pe = 1 means the solvent in the viscous state ?

Thank you

Zen
 
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This can't be the complete problem statement. Please provide the complete problem statement, with its exact wording.

Chet
 
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Hi Chet, This is the full question
upload_2015-4-24_22-24-50.png

upload_2015-4-24_22-22-53.png


Thanks
 

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If I understand correctly, you have completed parts a, b, and c, and now you want want to determine the answer to part d, correct? If so, what was your answer to part c.

Chet
 
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Hi Chet !

Yes you are right I have done part a-c. My answer on C was 0.05 m/s

Thanks

Zen
 
hizen_14 said:
Hi Chet !

Yes you are right I have done part a-c. My answer on C was 0.05 m/s

Thanks

Zen
Are you sure about that average velocity of the particles? It seems awfully large.

Chet
 
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Thanks Chet

I have changed the radius of particle from 100µm to 50µm but the velocity was larger than 50 µm. it doesn't make sense. :(

Vav = ((3kT)/m)1/2

Volume of particle = 4/3 πr3 = 4/3 π (50x10-9)3 = 5.236 x10-22 m3
Mass of particle = ρV = 1050 x 5.236x 10-22 = 5.498 x 10-19 kg

Vav = ((3x1.38 x 10-23 x 298 )/ 5.498 x 10-19 )1/2 = 0.149 m/s
 
I think this one is more reasonable ?

v = (2r2 Δρg) / 9η
= ( 2x( 50x10-9 )2 x (1050-1000) x 9.8) / (9 x 8.9x10-4)
= 3.059 x 10-10 m/s

THanks
 
hizen_14 said:
I think this one is more reasonable ?

v = (2r2 Δρg) / 9η
= ( 2x( 50x10-9 )2 x (1050-1000) x 9.8) / (9 x 8.9x10-4)
= 3.059 x 10-10 m/s

THanks
This is much better, if analyzed correctly. I can't vouch for that part of the calculation (because my experience is not in that area), but I can help you get the average shear rate at the particle surface once the particle velocity is established. Sometimes the shear rate is taken as the radial velocity gradient at the particle surface, and some times it is taken as the square root of the second invariant of the rate of deformation tensor. How is it defined in your situation?

Do you know the equations for the components in spherical coordinates of the velocity vector in Stokes flow past a moving sphere? If so, please write them down.

Chet
 
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  • #10
Hi Chet.

Chestermiller said:
Sometimes the shear rate is taken as the radial velocity gradient at the particle surface, and some times it is taken as the square root of the second invariant of the rate of deformation tensor. How is it defined in your situation?

I am not really sure about but I can see as the radial velocity gradient at the particle surface (dv/dx)

Chestermiller said:
Do you know the equations for the components in spherical coordinates of the velocity vector in Stokes flow past a moving sphere? If so, please write them down.

Fg-Fb-Fd = 0 at Terminal Velocity
where Fg = gravity force, Fb = buoyancy force and Fd = drag force.

Fg = (Vρpg)
Fb = (Vρfg)
Fd = 9πηrv

v = (2r2 Δρg) / 9η

I am not really sure this is what you asked for.

Thanks
 
  • #11
hizen_14 said:
Hi Chet.
I am not really sure about but I can see as the radial velocity gradient at the particle surface (dv/dx)
Fg-Fb-Fd = 0 at Terminal Velocity
where Fg = gravity force, Fb = buoyancy force and Fd = drag force.

Fg = (Vρpg)
Fb = (Vρfg)
Fd = 9πηrv

v = (2r2 Δρg) / 9η

I am not really sure this is what you asked for.

Thanks
I'm looking the equations for the components as a function of r and θ.

Chet
 
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  • #12
upload_2015-4-26_3-19-47.png


upload_2015-4-26_3-17-53.png
?
 

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