Maui
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Jano L. said:Well, hydrogens contribute with 2 electrons, oxygen with 8 electrons. They all move somewhere around the nuclei, and they all play the same role (the probability density is symmetric with respect to transposition of electrons). The covalent bond consist of strong correlation of the motion of the nuclei. It is maintained by the attractive force from the electrons, and has only as much stability as allowed by their motion. The stability of the bond in chemical bond theory based on Schr. equation is only probabilistic (tunnel effect...). The fact that the nuclei are close to each other does not break down immediately as some electron goes little bit farther from the hydrogen. The nuclei are very heavy and have great inertia with respect to the electrons; the hydrogen nucleus is 1836 times more heavier.
Of course, occasionally it may happen that this effect plus external forces lead to separation of hydrogen from the rest - there is some OH##^{-}## in the water too, but there is no obvious reason why motion along trajectories should break all the molecules into collection of isolated atoms.
Sorry, I don't see how your explanation shows that two electrons that are shared and on unique trajectories between two atoms can hold the two atoms together. The assertion that electrons follow unique trajectories(i.e. they are not in superposition of states) in atoms must be one of the wrongest claims I've read on this forum and reminds of early 20th century physics and Rutherford's model of the atom, which has been known to be wrong for a century(the paper you referenced that claims that background radiation keeps atoms from falling apart is wild speculation, not fact). There are areas where high levels of cosmic or environmental radiation are very unlikely to be found(e.g. the Earth's core) and yet the Earth is not know to have fallen apart.
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