Basic Thermodynamics; Change in U at Constant Pressure

[Silvius]

Homework Statement

What is the ΔU° at 25°C for the following reaction at constant pressure:

C_{2}H_{2} (g) + 5/2O_{2} (g) \rightarrow 2CO_{2} (g) + H_{2}O (g) ΔH° = -1299.5kJ

Homework Equations

ΔU = Q ± W
PV = nRT
W = PΔV

The Attempt at a Solution

Since we have constant pressure, ΔH° = Q, and since we are at standard conditions P = 1atm = 101.3kPa. Additionally T = 298K (which is given anyway). I try and find the work done on the system by finding the reduction in volume;

ΔV = ΔnRT/P

ΔV = (0.5 x 8.31 x 298)/101.3 = 12.2L

W_{on system} = 101.3kPa * 12.2L = 1238.2kJ

ΔU = -1299.5kJ + 1238.2kJ = -61.3kJ

However, the answer is -1298.3kJ.

Interestingly, this answer is what I would get if I had accidently calculated the W_{on system} was in joules and forgotten to convert - but I don't see how this can be the case - I'm dealing with kPa not Pa as my unit for pressure. Any help would be much appreciated!

 

[dimension10]

Homework Statement

What is the ΔU° at 25°C for the following reaction at constant pressure:

C_{2}H_{2} (g) + 5/2O_{2} (g) \rightarrow 2CO_{2} (g) + H_{2}O (g) ΔH° = -1299.5kJ

Homework Equations

ΔU = Q ± W
PV = nRT
W = PΔV

The Attempt at a Solution

Since we have constant pressure, ΔH° = Q, and since we are at standard conditions P = 1atm = 101.3kPa. Additionally T = 298K (which is given anyway). I try and find the work done on the system by finding the reduction in volume;

ΔV = ΔnRT/P

ΔV = (0.5 x 8.31 x 298)/101.3 = 12.2L

W_{on system} = 101.3kPa * 12.2L = 1238.2kJ

ΔU = -1299.5kJ + 1238.2kJ = -61.3kJ

However, the answer is -1298.3kJ.

Interestingly, this answer is what I would get if I had accidently calculated the W_{on system} was in joules and forgotten to convert - but I don't see how this can be the case - I'm dealing with kPa not Pa as my unit for pressure. Any help would be much appreciated!

That is because $E_{\mbox{int}}=Q+W$ applies when work is done on the system.

 

[Silvius]

That is because $E_{\mbox{int}}=Q+W$ applies when work is done on the system.

Work is being done on the system in this case; the pressure and temperature is constant, and so a decrease in the amount of gas results in a decrease of volume of the system. That is, the surrounding constant pressure is doing work in compressing the system.

Either way, I have found my error - it was simply an error in dimensional analysis! 1kPa * 1L = 1J, not kJ! Whoops!