Behavior of polypyrrole nanowires

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Discussion Overview

The discussion centers on the behavior of polypyrrole nanowires as observed through IV tests, specifically focusing on the observation of time-varying resistance and its potential causes. The scope includes experimental observations and interpretations related to electrical engineering and materials science.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Experimental/applied

Main Points Raised

  • One participant reports observing a time-varying resistance in polypyrrole nanowires that appears linear over three time periods, suggesting possible transport phenomena or polarization effects.
  • Another participant questions the definition of "time period" and raises the possibility of heating effects influencing the measurements, indicating a need for more details about the experimental setup.
  • A request for a plot of the data is made to aid in understanding the observed behavior.
  • Concerns are raised about how time-dependence is interpreted from the plot, with suggestions that non-linearity could arise from various factors, such as phonons, rather than a clear time-varying resistance.
  • Further inquiries are made regarding the measurement methodology, including whether a constant sweep rate is used or if measurements are taken at fixed values over time, to clarify the nature of the observed plateau in the I-V plot.

Areas of Agreement / Disagreement

Participants express differing views on the interpretation of the observed data and the potential causes of the time-varying resistance. There is no consensus on the nature of the time-dependence or the influence of external factors such as heating.

Contextual Notes

Limitations in the discussion include a lack of detailed information about the measurement conditions, such as the sweep rates and the specific experimental setup, which may affect the interpretation of the results.

Who May Find This Useful

This discussion may be of interest to students and researchers in electrical engineering, materials science, and those studying the electrical properties of conductive polymers.

abburiaditya
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I have been running IV tests on polypyrrole nanowires and i see a time varying resistance that is linear over 3 time periods...

can somebody explain this to me?? i am basically a EE student and i need help with the this... maybe it has to do with transport in the wires or some kind of polarization taking place in the wires that is causing the resistance to vary over time.
 
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What defines a "time period"? Are you sure you are not seeing heating effects?

Need to know all details about the measurements to be able to comment further...
 
here's a plot of the data that i have... can this help explain?
 

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How do you see the time-dependence in that plot? All I see is a non-linearity that could result from any of several possibilities (phonons, for instance).

Can you tell me how the measurement is made? Do you use a constant sweep rate for the current/voltage or do you fix it at a particular value and measure there for some length of time?

Again, I don't understand how you say there's a time dependence unless you measure at different sweep rates (or residence times) and the position of the plateau changes in V, but not in t. Do you have more data to suggest a time-dependence, or are you asking for a possible explanation of the plateau in the I-V plot?
 
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