Boltzmann statistics - finding the number of particles

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The discussion centers on applying Boltzmann statistics to determine the number of metal particles in a water column at different heights. The problem involves calculating the change in potential energy using gravitational force and buoyancy, with given parameters like particle radius, temperature, and density. Participants emphasize the need to express density as a function of height, which requires utilizing the Boltzmann distribution to account for energy states. There is confusion about how to integrate the Boltzmann formula into the solution process. Ultimately, understanding the relationship between particle density and height is crucial for solving the problem effectively.
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Boltzmann statistics -- finding the number of particles

Homework Statement


A column of water contains fine spherical metal particles of radius 2 x10-8m, which are in thermal equilibrium at 25C. If there are 1000 particles per unit volume at a given height, how many particles would be found in the same volum 1 mm higher? The density of the metal is 2 x104 kg m-3. Hint: use gravitational force and buoyancy in water and compute change in potential energy

Homework Equations


Fnet= \rhoVg - mg (\rho is density, V is volume, g is gravity, m is mass)

F*d = -mg \Deltah (h is height, d = height, F = Fnet

n(E) = g(E)fb(E) = A g(E)e-E/kT
n(E) = number of particles with energy E
g(E) = statistical weight of the state with energy E
A = normalization constant whose value depends of the system
k = Boltzmann constant
T = temperature
E = energy

The Attempt at a Solution



What I did was just substitute Fnet= \rhoVg - mg
into F*d = -mg \Deltah which gives me the change in potential energy. I'm not sure what to do with the boltmann distribution formula after that or do I even need it? I'm just stuck and don't know where to go. Any help will be appreciated

Thank you
 
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jianxu said:

Homework Statement


A column of water contains fine spherical metal particles of radius 2 x10-8m, which are in thermal equilibrium at 25C. If there are 1000 particles per unit volume at a given height, how many particles would be found in the same volum 1 mm higher? The density of the metal is 2 x104 kg m-3. Hint: use gravitational force and buoyancy in water and compute change in potential energy

Homework Equations


Fnet= \rhoVg - mg (\rho is density, V is volume, g is gravity, m is mass)

F*d = -mg \Deltah (h is height, d = height, F = Fnet

n(E) = g(E)fb(E) = A g(E)e-E/kT
n(E) = number of particles with energy E
g(E) = statistical weight of the state with energy E
A = normalization constant whose value depends of the system
k = Boltzmann constant
T = temperature
E = energy

The Attempt at a Solution



What I did was just substitute Fnet= \rhoVg - mg
into F*d = -mg \Deltah which gives me the change in potential energy. I'm not sure what to do with the boltmann distribution formula after that or do I even need it? I'm just stuck and don't know where to go. Any help will be appreciated

Thank you

you need the density as a function of height. that's why you need the boltmann distribution function for the density.
 

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