Bond Dissociation Energy of 2Cl: 58 kcal/mole

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SUMMARY

The bond dissociation energy of Cl2 is definitively 58 kcal/mole, indicating that this energy is required to dissociate the molecule into two chlorine atoms (2 Cl). The reaction Cl2 → 2 Cl is endothermic, as it involves a positive enthalpy change (ΔH° = +58 kcal/mol), meaning heat is absorbed during the process. This clarification helps to distinguish between bond dissociation energy and entropy terms, which are often confused in discussions about thermodynamics.

PREREQUISITES
  • Understanding of bond dissociation energy
  • Basic knowledge of thermodynamics, specifically enthalpy and entropy
  • Familiarity with chemical reaction notation
  • Concept of endothermic vs. exothermic reactions
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  • Study the concept of bond dissociation energy in detail
  • Learn about enthalpy changes in chemical reactions
  • Explore the differences between endothermic and exothermic reactions
  • Review thermodynamic principles related to heat transfer in reactions
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Chemistry students, educators, and professionals interested in thermodynamics and chemical reaction dynamics will benefit from this discussion.

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Given: Cl2 = 58 kcal/mole ------> 2cl

1. 58 kcal/mole is the bond dissociation energy T F

2. 58 kcal/mole is an entropy term T F

3. this reactin is endothermic T F

I don't understand get it! Any help woud be appreciated.
 
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Did you mean to write Cl_2+58 kcal/mole \rightarrow 2 Cl?

If so, then think about what it means. What is happening when Cl_2 \rightarrow 2 Cl?

What are you doing with the energy?

Can it be the 'entropy' term?
 
Thats one notation. Most textbooks nowadays would say

Cl_2 \longrightarrow 2 Cl \ \ \ \ \Delta H^0 = +58 \ \ kcal/mol

to avoid confusion about the "energy" change in the system. (At constant pressure, enthalpy = heat added or lost)

A positive enthalphy change corresponds with heat being absorbed by the system. A negative enthalpy change corresponds to heat being released by the system.
 
Thanks for the explanations :). The formula makes sense now!
 

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