Calculate % Excitation of Sample X w/ Laser Pulsed Source

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SUMMARY

This discussion focuses on calculating the energy required to excite 5% of a sample X in gas phase using a pulsed laser source emitting at 532nm. The absorption coefficient of the sample is 9.895e-18 cm² molecule⁻¹. The relationship between power and energy is established through the formula E=power/rep.rate, and the number of photons can be calculated using E=Nhc/lambda. The fluence can also be determined by measuring the spot size of the focused laser beam.

PREREQUISITES
  • Understanding of laser physics, specifically pulsed laser operation.
  • Knowledge of absorption coefficients and their significance in photonics.
  • Familiarity with the equations E=power/rep.rate and E=Nhc/lambda.
  • Experience with measuring spot size and calculating fluence in laser applications.
NEXT STEPS
  • Research the calculation of energy thresholds for excitation in photonic systems.
  • Learn about the significance of absorption cross sections in laser-material interactions.
  • Explore methods for measuring and calculating laser fluence accurately.
  • Investigate the principles of photon counting and its applications in spectroscopy.
USEFUL FOR

This discussion is beneficial for physicists, optical engineers, and researchers working with laser excitation of gases, particularly those interested in photonics and spectroscopy applications.

sciphys1
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Hi Everyone,

I am new to this forums. I am not sure where to post but general discussion is a good place. I am trying to figure out a problem:

I have a sample X in gas phase. Say it has an absorption coefficient of 9.895e-18 cm2 molecule-1 @ 532nm. I have a laser pulsed source (say 50 Hz) giving me 532nm light. How does one calculate what energy one needs to excite 5% or any percentage of the sample? The measured power of the pulsed laser is related to the energy by:

E=power/rep.rate

and one can use this to calculate the number of photons N,by

E=Nhc/lambda where lambda is the wavelength (in the example above it is 532nm).

we can also calculate the fluence by measuring the spot size as we focus the laser beam into the sample. I can't figure out how people choose the energy/power from absorption cross section calculations? I am a novice, so need a little help please. Thank you.

sciphys1
 
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