Calculating Internal Energy Change in a Gas Under Constant Pressure

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Homework Help Overview

The discussion revolves around calculating the change in internal energy of a gas that is compressed at a constant pressure while heat is leaving the system. The subject area includes thermodynamics, specifically focusing on work done on a gas and internal energy changes.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • Participants explore the calculations for work done on the gas and the change in internal energy. Questions arise regarding the correct value of heat leaving the gas, with some participants checking for consistency in the values used.

Discussion Status

The discussion is active, with participants providing feedback on the calculations and identifying potential errors in the values used for heat transfer. There is a productive exchange regarding the correct interpretation of the problem statement and the values involved.

Contextual Notes

Participants note discrepancies in the values for heat leaving the gas, which affects the calculations for internal energy change. The problem is set within the constraints of a homework assignment that requires electronic submission and grading.

duds1234
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Hello, this is my first post, so I apologize in advance if it's not quite up to par.

Homework Statement



A gas is compressed at a constant pressure of 0.639 atm from 5.41 L to 2.3 L. In the process, 470 J of energy leaves the gas by heat.
a) What is the work done on the gas (J)?
b) What is the change in its internal energy(J)?

Homework Equations



a) ##W=-PΔV##
b) ##ΔU=Q+W##

The Attempt at a Solution



a)
##P = 0.639atm {\frac{1Pa}{9.872*10^-6atm}} = 64728.52512Pa##
##ΔV = V_f - V_i = 2.3L - 5.41L = -3.11L {\frac{1*10^{-3}m^3}{1L}} = -0.00311m^3##
##W = -P ΔV = -6.4728.52512Pa * -0.00311m^3 = 201.3057131J##

I submitted my answer to part a and it was correct. Part b is what I need help with. I believe that I am doing it correctly, but my answer is returned as incorrect. My incorrect work and answer appears below.

b)
##ΔU = Q + W = -407J + 201.3057131J = -205.6942869J##

Any insight into why my work/answer for part b is incorrect would be greatly appreciated!
 
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If your answer to part a is correct, then I can't see what's wrong with your answer to part b (see EDIT)

Is this a multi choice question that is automatically assessed?

EDIT: Just noticed that in the question statement you say that 470J of energy leaves, but in the calculation for part b you use the figure 407J
 
Last edited:
Unfortunately, this isn't a multiple choice question. I have to submit my answers electronically and a computer grades them. I have confirmation that part a is correct and that my answer for b is incorrect.
 
Ok. Can you confirm which value of heat leaving the gas is correct: 407 J or 470 J
 
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It is 470, thus this would be my error in part b. Thank you very much for helping me find my silly mistake. The correct answer would be -268.6942869J.
 
You're welcome. It happens to everyone now and then!
 

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