Calculating Kp for a Gas-Phase Equilibrium Reaction

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SUMMARY

The discussion centers on calculating the equilibrium constant Kp for the gas-phase reaction Xe(g) + 2F2(g) → XeF4(g). Given the initial pressures of 2.24 atm for Xe and 4.27 atm for F2, and the equilibrium pressure of Xe at 0.34 atm, the correct calculation of Kp results in a value of 25. The decrease in Xe pressure indicates its conversion into XeF4, necessitating the determination of the partial pressures of all species at equilibrium to accurately compute Kp.

PREREQUISITES
  • Understanding of gas-phase equilibrium reactions
  • Knowledge of the equilibrium constant expression (Kp)
  • Familiarity with partial pressure calculations
  • Basic concepts of stoichiometry in chemical reactions
NEXT STEPS
  • Calculate partial pressures of XeF4 at equilibrium
  • Review the derivation of the Kp expression for gas-phase reactions
  • Study the impact of initial concentrations on equilibrium positions
  • Explore related concepts in Le Chatelier's principle
USEFUL FOR

Chemistry students, chemical engineers, and anyone studying gas-phase reactions and equilibrium constants.

rcrx
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A reaction mixture initially contains 2.24 atm Xe and 4.27 atm F2. If the equilibrium pressure of Xe is 0.34 atm, determine Kp for the reaction.

This question came out of the blue, and all I can think of is that Kp=(PXe)(PF2), but the answer is supposed to be 25.

I don't get it? Any suggestions? Thanks!
 
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Initial pressure of Xe was 2.24 atm, at equilibrium it was 0.34 atm. What have happened to the rest of Xe?

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methods
 
It must have left the container? I don't know, really :\
 
Question asks about reaction equilibrium constant... What reaction?

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Oh, sorry. Xe(g) + 2F2(g) ---> XeF4(g)
 
So again, what happened to the rest of the Xe?
 
The rest of Xe has gone to the formation of XeF4
 
Can you now figure out the partial pressures of all species at equilibrium?

And take another look at the expression you have for Kp (compare with the equation in post#5).
 

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