Calculating Reversible Work and Irreversibility in a Filling Container

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SUMMARY

The discussion focuses on calculating reversible work and irreversibility in a rigid, evacuated container that fills with atmospheric air. The first law of thermodynamics is applied, with the equation Q + minhin = m2u2 guiding the analysis. Key findings indicate that the irreversible work (Wirrev) is zero, while the reversible work (Wrev) represents the theoretical maximum work achievable. The irreversibility (I) is quantified as I = Wrev - Wirrev, leading to the conclusion that the irreversibility equals the work done by the atmosphere on the container, expressed as I = P0.V.

PREREQUISITES
  • Understanding of the first law of thermodynamics
  • Familiarity with concepts of reversible and irreversible processes
  • Knowledge of thermal equilibrium and mechanical equilibrium
  • Basic principles of work and energy in thermodynamic systems
NEXT STEPS
  • Study the implications of the first law of thermodynamics in closed systems
  • Explore the concept of thermal and mechanical equilibrium in detail
  • Investigate the differences between reversible and irreversible work in thermodynamics
  • Learn about the calculation of work done in various thermodynamic processes
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Students and professionals in thermodynamics, mechanical engineers, and anyone involved in energy systems analysis will benefit from this discussion.

albertov123
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Homework Statement


A rigid and evacuated container of volume V that is surrounded by atmosphere (P0, T0). At some point neck valve opens and atmospheric air gradually fills the container. The wall of container is thin enough so that eventually the trapped air and atm reach thermal equilibrium. The neck valve remains open, therefore at the end the trapped air and atmosphere are also in mechanical equilibrium. Calculate the reversible work and irreversibility.

Homework Equations

The Attempt at a Solution


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From the first law Q + minhin = m2u2

Qout = P0.V

Sgen=Q/T=P0.V/T0

I = T0S = P0.V = I

I = Wrev - Wirrev

How can I find reversible work? I assumed work is zero in first law. But which work was that irreversible or reversible I don't know.
 
Last edited:
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The irreversible work is the shaft work, which you correctly determined to be zero. The reversible work is a theoretical quantity, representing the work that could have been done. The irreversibility is the lost work.
 

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