Calculating the number of energy states using momentum space

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Discussion Overview

The discussion revolves around calculating the number of possible energy states in a two-dimensional momentum space for a particle confined within a box. Participants explore the implications of momentum direction, the shape of the container, and the relationship between momentum states and the dimensions of the box.

Discussion Character

  • Exploratory
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant questions the assumption that the density of energy states is homogeneous across momentum space, suggesting that the number of states should depend on the length of the box in the direction of the momentum vector.
  • Another participant challenges the idea that the number of energy states is independent of the shape of the container, arguing that the number density is dependent on the length of the box.
  • Some participants provide examples and references to support their claims about the relationship between momentum and spatial dimensions, indicating that the number of states in momentum space may differ based on the direction of the momentum vector.
  • There is a discussion about the implications of using different shapes for the container, with references to how this affects the calculations of energy states.
  • Clarifications are made regarding the relationship between momentum states and the dimensions of the box, with some participants asserting that the number of states is indeed dependent on the box dimensions in the direction of the momentum.
  • One participant expresses confusion about the derivation of formulas relating to the number of states and the dimensions of the box, indicating a need for further clarification on the mathematical relationships involved.

Areas of Agreement / Disagreement

Participants express differing views on whether the number of energy states is independent of the shape of the container and how momentum direction affects the number of states. The discussion remains unresolved, with multiple competing perspectives presented.

Contextual Notes

Participants reference specific formulas and examples from literature, indicating that the discussion is grounded in mathematical reasoning but also highlights the complexity and potential for misunderstanding in the relationships between momentum and spatial dimensions.

  • #151
JohnnyGui said:

StackExchange is not a valid source. If you can find a textbook or peer-reviewed paper that makes this claim, we can discuss it.

JohnnyGui said:
I have never seen a number of particles function in the continuous approach without the need to integrate one of its functions.

Yes, whenever you're dealing with a continuous spectrum the only quantities that will be meaningful when comparing with experiment will be integrals.
 
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  • #152
Does the formula in my previous post agree with what you're saying?

Also, how does this...

PeterDonis said:
I have never seen it written with a dEdEdE if it's not in an integral.

...coincide with your previous statement:

PeterDonis said:
Yes, whenever you're dealing with a continuous spectrum the only quantities that will be meaningful when comparing with experiment will be integrals.

Isn't it then obvious that you won't ever find a function without an integral for the continuous approach?

Where is the particle number function ##n(E)## for the continuous approach that doesn't have any integral, in which the quantum states function ##g(E)## is not written in terms of Density of States times ##dE##?
 
  • #153
JohnnyGui said:
Isn't it then obvious that you won't ever find a function without an integral for the continuous approach?

No, because some of the very sources you linked to in this thread show the function without an integral, in their derivations of the function, and make no claim that their derivations only apply to the discrete approach. But they also don't try to link that function to any particular experimental results.

JohnnyGui said:
Where is the particle number function ##n(E)## for the continuous approach that doesn't have any integral

We've already been over this. You're making this way harder than it needs to be. You have a function with one argument, ##E##. You can plug any number you want into that function and get another number. You can also integrate that function over a range of arguments and get a number; and when you do the integral you need to include the ##dE## because that's how integration works.

JohnnyGui said:
in which the quantum states function ##g(E)## is not written in terms of Density of States times ##dE##?

You're confusing yourself with sloppy language. The function ##g(E)## is never "written in terms of Density of States times ##dE##". It is not a function of ##dE##. It's a function of ##E##. When you integrate it over a range of values of ##E##, you have to include ##dE## in the integrand because that's how integration works. That's really all there is to it.
 
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  • #154
PeterDonis said:
The function g(E)g(E)g(E) is never "written in terms of Density of States times dEdEdE". It is not a function of dEdEdE. It's a function of EEE. When you integrate it over a range of values of EEE, you have to include dEdEdE in the integrand because that's how integration works. That's really all there is to it.

Apparently I misunderstood the part how ##g(E)## is transformed for the integrand to work. The way ##g(E)## is transformed to include it in the integrand supports the explanation of the replier at StackExchange.

##g(E)## gives the number of quantum states for a particular energy ##E## and is 1/8th of a sphere surface in n-dimensions:
$$g(E) = \frac{4 \pi mL^2 \cdot E}{h^2} = 4\pi r^2 \cdot \frac{1}{8}$$
From this:
$$r=\sqrt{\frac{8mL^2\cdot E}{h^2}}$$
For the integrand for the continuous approach, one would want to calculate the number of quantum states over a range ##dE##, which is the surface of 1/8th of an n-sphere times a thickness ##dr##
$$g(E\geq E+dE) = \frac{4 \pi mL^2 \cdot E}{h^2} \cdot d(\sqrt{\frac{8mL^2\cdot E}{h^2}})$$
The ##dr## can be wirtten as:
$$dr = d(\sqrt{\frac{8mL^2\cdot E}{h^2}}) = \frac{\sqrt{2}\cdot mL}{h\cdot \sqrt{mE}}\cdot dE$$
Substuting ##dr## with this in ##g(E \geq E + dE)## and simplifying gives:
$$g(E\geq E+dE) = \frac{2^{2.5}\pi \cdot m^{1.5} \cdot V \cdot \sqrt{E}}{h^3}\cdot dE$$
Since the number of quantum states in the energylevels within ##dE## doesn't change much, one can multiply this ##g(E \geq E+dE)## by the number of particles per 1 quantum state at a particular energy ##E##, which is ##\frac{N}{Z} \cdot e^{-\beta E}##, giving the formula in my previous post #150 that the replier at StackExchange explained.
 
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