sodium.dioxid
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In a cylinder (with a piston) containing gas, why do we use the external pressure, instead of the pressure of the gas, to calculate work?
In gas cylinders, external pressure is used to calculate work instead of internal pressure because internal forces cancel each other out, making external pressure a more stable reference. The work done by the gas during expansion is defined by the equation dW = p dV, where p represents external pressure. For isothermal expansion, the work can be calculated using the formula Work = nRT ln(V2/V1), derived from the ideal gas law PV = nRT. This approach simplifies understanding the work done on the system by the surroundings.
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Woopydalan said:I think it would be because all the internal forces cancel each other out.
sodium.dioxid said:In a cylinder (with a piston) containing gas, why do we use the external pressure, instead of the pressure of the gas, to calculate work?
Infinitum said:Internal pressure changes in all processes except isobaric. External pressure does not. Also, the work done on the system by the surrounding is easier to understand in terms of external pressure.