Calculations of Solubility Product of Lead 2 Chloride

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SUMMARY

The discussion centers on the calculations of the solubility product constant (Ksp) for Lead(II) Chloride (PbCl2). The user calculated a Ksp of 9.17 based on concentrations of Pb at 6.12 x 10^-5 mol/L and Cl at 1.224 x 10^-4 mol/L. However, the correct Ksp value for PbCl2 at 25 degrees Celsius is approximately 1.6 x 10^-5. To determine if a precipitate forms when mixing 100.0 mL of 0.02 mol/L lead(II) nitrate and 100.0 mL of 0.02 mol/L sodium chloride, the ionic product must be calculated and compared to the Ksp.

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  • Understanding of solubility product constant (Ksp)
  • Knowledge of ionic product calculations
  • Familiarity with molarity and concentration
  • Basic principles of chemical equilibrium
NEXT STEPS
  • Learn how to calculate ionic products for precipitation reactions
  • Study the solubility product constant (Ksp) for various salts
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aisha
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HELP! In this experiment I measured the initial mass of a piece of Al and then i put it into a beaker containing 100.0 mL of saturated PbCl2

The concentration I calculated for Pb is 6.12 *10^-^5 mol/L
The concentration I calculated for Cl is 1.224* 10^-^4 mol/L

Therefore my Ksp= [Pb] [Cl]^2
=[6.12*10^-^5] [1.224*10^-^8]^2
Ksp=9.17
This is what I calculated please verify

I need help answering this question if 100.0 ml of 0.02 mol/L lead 2 nitrate solution and 100.0 ml of 0.02 mol/L sodium chloride solution were combined would a precipitate of Lead 2 chloride be expected to form? I have to show all my work. But I am not sure where to start.
 
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G'day, Aisha.

The first part of your post is a little confusing.

How did you calculate [Pb2+] and [Cl-]?

If these concentrations are indeed in a saturated solution then Ksp(PbCl2) = 9.16x10^(-13), just a couple of typos there.

At 25 degrees C, the Ksp of PbCl2 is about 1.6x10^(-5), so perhaps the room was cold?

If the second part is connected to the first part, then you are probably to find the ionic product (given by [Pb2+][Cl-]^2) and compare it to the Ksp value obtained earlier. Hint: for the same amount, doubling the volume halves the concentration. If IP > Ksp, a precipitate will form.

~ ~ ~ ~ ~ ~

I'm new here but I think this belongs in the Science Education forum.
 
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