You follow the arrow for i2: You will cross 4 resistors looping around, with the value R. therefore i2 results in a voltage drop = -4*R*i2.
One of the resistors in the loop is crossed by the current i3 in opposite direction, which yield a voltage rise = R*i3.
One other resistors is crossed by the current i1 in opposite direction, which yield a voltage rise = R*i1.
The sum of all these voltage changes must be zero, thus:
-4*R*i2 + R*i3 + R*i1 = 0.
Setting R = 1Ω, this can be rewritten:
-4*i2 + i3 + i1 = 0
Be very careful with the signs. ( That's why you have to make a drawing, so that you know what you are doing ). Having calculated the currents, remember to divide their values by 6, as the real value for R is 6Ω ( not 1Ω ).