Can polyester resin eventually cure if it was too cold at first?

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Discussion Overview

The discussion revolves around the curing process of polyester resin that was initially exposed to cold temperatures. Participants explore whether the resin can eventually cure after being kept in a cold environment and the implications of using catalysts in such conditions. The conversation includes practical advice, personal experiences, and references to external resources related to resin curing in cold weather.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant reports that after heating the resin to about 30°C for 3 hours, it still emits an uncured smell, questioning whether it will ever cure or if it is ruined.
  • Another participant notes that paint and varnish can be ruined by freezing temperatures and references an article suggesting that curing may take a long time, implying it might still work out.
  • Several participants share links to articles about resin curing in cold weather, indicating a shared interest in finding solutions.
  • Concerns are raised about the potential damage to the catalyst and resin after being left outside in below-freezing temperatures, with one participant asserting that it was preserved but highlighting issues with mixing the catalyst in cold conditions.
  • One participant recounts a personal experience where polyester resin took a week to set during a cold snap, suggesting that patience may be required.
  • Another participant inquires about the current state of the resin, asking if it has gelled or still flows, and offers suggestions for maintaining heat and improving curing conditions, including the use of a polythene tent and UV grow lights.

Areas of Agreement / Disagreement

Participants express varying opinions on whether the resin will eventually cure, with some suggesting it may take time while others share personal experiences that indicate it can cure under the right conditions. There is no consensus on the outcome, and multiple views on the effectiveness of different heating methods are presented.

Contextual Notes

Participants mention the importance of proper mixing of the catalyst and the effects of temperature on diffusion rates, indicating that the discussion is limited by assumptions about the specific conditions and materials involved.

mess
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TL;DR
I mixed polyester resin in around 5°C and overnight it went to -10, and for the next few days it was too cold to cure.
I finally brought in a heater and kept it at about 30C for 3 hours. It still smells like uncured offgassing. Will it ever cure or did the freezing/prolonged cold ruin it and i have to remove it?
 
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I also left the catalyst and resin outside in below freezing temperature, is there a chance i damaged it?
 
mess said:
I also left the catalyst and resin outside in below freezing temperature, is there a chance i damaged it?
No. You preserved it.
The problem with cold resin is mixing the catalyst into the thick cold resin. Poor mixing requires longer for the catalyst to diffuse or migrate through the mix. Diffusion is very poor at low temperatures. The heat generated by the reaction will accelerate the reaction, unless that heat is rapidly lost to a cold environment, in which case you must wait for the environment to warm.
I once waited for a week during a cold snap for polyester resin to set. It took another week before I could remove it from the mold.
 
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Baluncore said:
No. You preserved it.
The problem with cold resin is mixing the catalyst into the thick cold resin. Poor mixing requires longer for the catalyst to diffuse or migrate through the mix. Diffusion is very poor at low temperatures. The heat generated by the reaction will accelerate the reaction, unless that heat is rapidly lost to a cold environment, in which case you must wait for the environment to warm.
I once waited for a week during a cold snap for polyester resin to set. It took another week before I could remove it from the mold.

Its been about 3 weeks now and it still stinks :/ I've since put a IR heat lamp on it for about 12 hours total, with no change in smell. it smells like freshly mixed resin, not as strong, but it still smells when i go up close to it.
 
Has it gelled yet, or does it still flow? Is it like rubber?

It will continue to smell for quite a while. If it smells different to plain resin, then it is reacting, and you did remember to put the catalyst in. The smell will permeate grains, flour and similar products.

What is the size and shape of the item? If it is a thin laminate it will reflect or radiate as much heat as you can provide. Maybe you need to make a polythene tunnel or tent, supported by hoops or wires. Use a fan heater and circulate air continuously throughout the chamber. Maintain a stable 20°C for 6 hours.

Just an idea. You have tried IR, but you might benefit from “UV grow lights”. Catalyst reacts very rapidly in direct sunlight due to the UV.
 

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