Carnot cycle with efficiency > 1

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Discussion Overview

The discussion centers around the theoretical possibility of constructing an engine that operates on the Carnot cycle using two reservoirs with temperatures T_1<0

Discussion Character

  • Debate/contested
  • Conceptual clarification

Main Points Raised

  • Some participants propose that it is theoretically possible to construct an engine using a Carnot cycle with a negative temperature reservoir, suggesting that this could lead to an efficiency greater than 1.
  • Others argue against this possibility, stating that negative temperatures do not correspond to a physical reality that allows for efficiencies greater than 1, as they are defined in a way that does not align with traditional thermodynamic principles.
  • A participant questions the logic of having a cold reservoir that is "hot" and a hot reservoir that is "cold," suggesting that plugging these values into the efficiency equation would yield nonsensical results.
  • Another participant emphasizes that temperature scales using negative values are more about human convenience and do not reflect absolute physical realities, advocating for the use of the Kelvin scale, which does not allow for temperatures below absolute zero.
  • One participant explains that negative temperatures, while numerically lower, are actually higher than infinite temperatures, complicating the energy balance in the Carnot cycle.

Areas of Agreement / Disagreement

Participants generally disagree on the feasibility of achieving efficiencies greater than 1 with a Carnot cycle involving negative temperatures. Multiple competing views remain, with some supporting the theoretical possibility and others firmly rejecting it based on thermodynamic principles.

Contextual Notes

There are unresolved assumptions regarding the definitions and implications of negative temperatures, as well as the mathematical treatment of the Carnot cycle in this context. The discussion reflects a range of interpretations and understandings of thermodynamic concepts.

paweld
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Is it possible (at least theoretically) to construct engine which uses Carnot cycle
and two reservoirs with temperatures [tex]T_1<0<T_2[/tex] (one of them has
negative temperature which is possible e.g. in case of two-state paramagnet).
Such cycle would have efficiency greater then 1.

(of course the reservoir with negative temperature is "hotter")
 
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No. Please see earlier threads.
 
paweld said:
Is it possible (at least theoretically) to construct engine which uses Carnot cycle
and two reservoirs with temperatures [tex]T_1<0<T_2[/tex] (one of them has
negative temperature which is possible e.g. in case of two-state paramagnet).
Such cycle would have efficiency greater then 1.

(of course the reservoir with negative temperature is "hotter")
I'm not following - you want the cold reservoir to be hot and the hot reservoir to be cold? If you plug that into the efficiency equation, you get an efficiency below zero! In other words, nothing.

And a temperature below zero...you mean below absolute zero? :confused:

http://en.wikipedia.org/wiki/Carnot_cycle
 
paweld said:
Is it possible (at least theoretically) to construct engine which uses Carnot cycle
and two reservoirs with temperatures [tex]T_1<0<T_2[/tex] (one of them has
negative temperature which is possible e.g. in case of two-state paramagnet).
Such cycle would have efficiency greater then 1.

(of course the reservoir with negative temperature is "hotter")

Temperature conventions that use negative values do not do so for any absolute physical reasons. They are more designed around human convenience (water's state changes for Celsius and I think human comfort for Farenheit).

That is why we have the Kelvin scale. You can't go below 0 Kelvin because the Kelvin temperature relates directly to energy, which can't be negative. Kelvin best represents the actual thermodynamics, which doesn't allow for a negative number.
 
Sounds like meaningless twaddle to me.
 
paweld said:
Is it possible (at least theoretically) to construct engine which uses Carnot cycle
and two reservoirs with temperatures [tex]T_1<0<T_2[/tex] (one of them has
negative temperature which is possible e.g. in case of two-state paramagnet).
Such cycle would have efficiency greater then 1.

(of course the reservoir with negative temperature is "hotter")

No. The reason is that negative temperatures, although numerically lower than zero, are higher than infinite temperature. From http://en.wikipedia.org/wiki/Negative_temperature#Heat_and_molecular_energy_distribution":

"The temperature scale from cold to hot runs:

+0 K, . . . , +300 K, . . . , +∞ K, −∞ K, . . . , −300 K, . . . , −0 K."

On the "other side", everything works in reverse: when you add energy, the temperature decreases; when you remove energy, the temperature increases. So let's assume you have a Thot that is negative and a Tcold that is positive. Going from Thot to −∞ K, you will need to add energy. Then going from +∞ K to some temperature Tx you will recover the amount of energy you spent "cooling" your negative temperature, making your net energy balance = 0. Finally going from Tx to Tcold will represent the actual energy you will recover. So the actual Carnot cycle have to be calculated with Tx as the hotter temperature.

Not a pro on the subject, that is just my understanding.
 
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