Chemistry- Electron Affinity very confused

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SUMMARY

The discussion focuses on ranking atoms by their electron affinity (EA), specifically comparing Lithium (Li), Hydrogen (H), and Helium (He). The consensus is that the order from smallest to largest electron affinity is G (Li), H, and K (He), with the understanding that ionization energy (IE) and electron affinity are related but distinct concepts. The relationship between these two properties is clarified, emphasizing that while both measure an atom's tendency to interact with electrons, they do so in different contexts: IE measures energy required to remove an electron, while EA measures energy change when an electron is added.

PREREQUISITES
  • Understanding of electron affinity and ionization energy concepts
  • Familiarity with atomic structure and electron configurations
  • Knowledge of the octet rule in chemistry
  • Basic grasp of energy changes in chemical reactions
NEXT STEPS
  • Research the electron affinity trends across the periodic table
  • Study the relationship between ionization energy and electron affinity in detail
  • Explore the concept of the octet rule and its implications on electron affinity
  • Learn about the energy changes associated with adding electrons to different elements
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Chemistry students, educators, and anyone seeking to deepen their understanding of atomic properties and their implications in chemical behavior.

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Homework Statement


e3-16.gif

Rank the atoms in electron affinity, from smallest to largest.


Homework Equations



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The Attempt at a Solution



G has the highest energy, followed by H then K. I looked at the diagram and saw that-
G= 1s^2 2s^1 (Li)
H= 1s^1 (H)
K= 1s^2 (He)

I know that ionization energy and electron affinity both are very high at F. There was a question about the IE, and I got it right as GHK. I thought that IE and EA were related to each other...IE is the want to become a cation (Which the top right surely doesn't want to do), and EA is the change in E when an e- is added...adding an e- to F takes a lot of E, but it's very stable.

I thought that the EA from low to high is the same as IE (GHK). I don't see why it isn't.
 
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They tend to follow the same trend, because they both measure how much an atom 'likes' electrons. The details are a little different however. You're definitely on the right track: IE is how much energy is required to remove an electron, and EA is how much energy is gained when an electron is added.

Looking at the atoms in the figure, compare the energy of the current state with the energy of adding another electron (think about the octet rule mostly); which atom would be 'happiest' to gain an electron?
 

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