Compare the Bond lengths of IO2F2 and IOF3

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SUMMARY

The discussion centers on the comparison of bond lengths between IO2F2- and IOF3. Participants conclude that IOF3 has a larger average bond length due to its structure, which includes three single bonds and one double bond, compared to IO2F2-, which has two double bonds and two single bonds. The confusion arises from the initial misidentification of IO2F2 as a valid compound, which was later corrected to IO2F2-. The consensus is that the average bond length comparison is meaningful only when the correct structures are considered.

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  • Chemical bonding concepts, including single and double bonds
  • Understanding of molecular structures and resonance
  • Knowledge of iodine oxides and their derivatives
  • Familiarity with bond length measurement techniques
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  • Research the molecular geometry of IO2F2- and IOF3
  • Study the effects of hybridization on bond lengths in chemical compounds
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  • Learn about bond length trends in halogen oxides
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Chemistry students, educators, and researchers interested in molecular structure analysis and bond length comparisons in halogen compounds.

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Homework Statement
Compare the average bondlengths of the following compounds

IO2F2 and IOF3
Relevant Equations
Bent rules

%S charecter inversly proportional to bond lenth
Okay So our Chemistry Professor gave us the answer as the following

IO2F2 has a larger bond length than IOF3

The reason being is once you draw the structures of the compounds IO2F2 has more number of double bonds that the later hence it shall have more p charecter than IOF3...hence it will have a larger avg bond length...but well i sort of don't undestand this logic

Well hear me out, so a single bond is larger than a double bond right, so IOF3
Has 3 single bonds, a lone pair and a double bond while IO2F2 has 2 single , 2 double bonds , and a lone pair...so due to the latger no of single bonds the avg bond length will be higher in IOF3

Yea so i think the answer is IOF3 has the larger avg bond length.(as opposed to my professor)

Could you please rectify me if I am wrong ?
Thank you :)
 

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IO2F2 doesn't exist. Do you mean IO2F2-?

Do you mean average length of all bonds, I-O and I-F? That doesn't seem to be a very meaningful comparison.
 
mjc123 said:
IO2F2 doesn't exist. Do you mean IO2F2-?

Do you mean average length of all bonds, I-O and I-F? That doesn't seem to be a very meaningful comparison.

The question was just compare average bond lengths. They didnt specify which bonds to compare

And yes, I am sorry the copound was IO2F2-
Im so sorry for that error
 
EDIT#1 - THe Question is to compare Average bond lengths of IO2F2- and IOF3There is an error in the Orignal post where i forgot to add the "-" superscript, sorry for the inconvinience
 
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I think you'd have too many electrons round I if you had two I=O double bonds in IO2F2-. In IOF3, replace one F by O- (with a single bond). The IO2 moiety should be O=I-O- ↔ O--I=O (not linear!)
 
mjc123 said:
I think you'd have too many electrons round I if you had two I=O double bonds in IO2F2-. In IOF3, replace one F by O- (with a single bond). The IO2 moiety should be O=I-O- ↔ O--I=O (not linear!)

I agree with this, but they gave the structure like that in the question.
(Im beginning to think this is a horribly framed question...Good job publishers ! Making us students life easier)
 

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