Concept of Entropy. (Question)

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Discussion Overview

The discussion revolves around the concept of entropy, particularly in the context of heating a metal and its subsequent radiation of energy in space. Participants explore the implications of the second law of thermodynamics and the behavior of entropy in closed and open systems.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant questions the behavior of entropy when heating a metal and suggests that the entropy of the metal decreases as it radiates energy.
  • Another participant prompts consideration of the energy source used to heat the metal, implying it affects the overall entropy change.
  • A participant notes that radiation itself has entropy and that the entire space should be considered a closed system in this context.
  • It is suggested that while the second law of thermodynamics states that entropy increases for irreversible changes, this applies to closed systems, and entropy can flow out of a system, allowing for local decreases.
  • Clarification is provided that when the metal radiates and cools, the total entropy of the system (metal plus space) increases.
  • Discussion includes the specifics of how entropy changes when heat is transferred from a high-temperature body to the metal, indicating that the total entropy must increase according to the second law.

Areas of Agreement / Disagreement

Participants express differing views on the implications of the second law of thermodynamics and the treatment of entropy in the context of radiation and energy transfer. There is no consensus on the specific mechanics of entropy change in the described scenario.

Contextual Notes

Participants highlight the importance of defining the system boundaries when discussing entropy changes, noting that assumptions about closed versus open systems significantly impact the conclusions drawn.

amk_dbz
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I have a question about the increasing behavior of entropy.
Suppose we heat a metal (Take for instance Fe) till it radiates energy and then put it in space (No medium). So the metal radiates energy in electromagnetic waves which decreases the entropy of the metal (Due to decrease in internal energy of metal. I hope so :smile:).On the other hand the E.M. waves will keep traveling in space (no medium.It might get absorbed by other objects but still space is quite large?)(The space will be the dump for this energy).So the net entropy change will be a decrease (due to decrease in the system (Fe metal)).But second law of thermodynamics states that entropy always increases for irreversible change.

Where have I gone wrong?

Help will be appreciated.Thank you :smile:.
 
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Have you considered the source of your energy you used to heat the metal?
 
The closed system here is your whole space - and radiation has entropy, too.
 
Drakkith said:
Have you considered the source of your energy you used to heat the metal?

Ok . If i heat the metal by keeping it in contact with body at high temperature T2 then it gives heat q to the metal , So entropy of the body at T2 decreases, right??
 
mfb said:
The closed system here is your whole space - and radiation has entropy, too.

Could you explain, please? I do not have deep knowledge in thermodynamics.:confused:
 
But second law of thermodynamics states that entropy always increases for irreversible change.
This is true for closed systems only. If you have some way to let entropy flow out, entropy of an object can decrease. This is done all the time when objects cool: They transfer entropy to the environment around them.

In your setup (radiating metal), you need some system where no entropy can leave (or enter) the system to use the second law of thermodynamics. This is "metal + all space where radiation from the metal is". In this system, entropy increases when the metal radiates and cools.
 
amk_dbz said:
Ok . If i heat the metal by keeping it in contact with body at high temperature T2 then it gives heat q to the metal , So entropy of the body at T2 decreases, right??
That is correct. If q is the amount of energy being conducted from the body, then the body decreases in entropy by an amount q/T2.
Assuming that all energy is being transported between body and metal. The total entropy in both the metal and the body has to increase according to the Second Law. Therefore, the entropy in the metal as to increase by an amount equal to or greater than q/T2.
The second law has just been used to predict that the increase of entropy in the metal has to be equal to or greater than q/T2. However, the second law by itself doesn't provide the exact value for the increase in entropy of the metal.
The increase in entropy in the metal has two parts. The component of entropy that equals q/T2 is said to be transferred from the body to the metal. The part of the increase in metal entropy that exceeds q/T2 is said to have been created.
 
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