Converting Transmission to Absorbance (Optics)

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SUMMARY

This discussion focuses on converting transmission data of various glasses in the infrared (IR) spectrum to absorbance, specifically addressing the relationship between transmission percentage and material thickness. The equation A = 2 - Log(T%) is mentioned, but its limitation regarding thickness is highlighted. The conservation of energy principle is introduced, stating that a + t + r = 1, where 'a' is absorbed light, 't' is transmitted light, and 'r' is reflected light. Beer's Law is presented as a critical formula for relating absorbance to thickness, expressed as I = I_0 * 10^(-al), where 'a' is the absorption coefficient and 'l' is the thickness of the material.

PREREQUISITES
  • Understanding of Beer's Law in optics
  • Familiarity with the concept of transmission and absorbance
  • Knowledge of energy conservation principles in physics
  • Basic mathematical skills for logarithmic calculations
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  • Study the application of Beer's Law in different materials
  • Research methods for measuring the absorption coefficient
  • Explore the impact of thickness on transmission and absorbance
  • Learn about the significance of reflection in optical measurements
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Optics researchers, materials scientists, and anyone involved in the analysis of light transmission through various materials, particularly in the infrared spectrum.

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I have taken data for the transmission vs. wavelength for several types of glasses in the IR. I want to convert this to absorbance so that I can generalize transmission to different thickness glasses.

I found an equation online that stated A = 2-Log(T%) (where Log is base 10). But I do not see how this considers thickness.

Does anyone know how I can translate knowing the transmission % for a specific thickness glass to knowing the absorbance/transmission to thicker glasses?
 
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There's a few simple formulas you can use. Starting with conservation of energy, a+t+r = 1, where 'a' is the fraction of absorbed light, 'r' the fraction of reflected light, and 't' the fraction of transmitted light.

If r = 0 (or the measurements are performed in such a way to allow r = 0), then a = 1-t. As you note, this can often be written in a way that accounts for a material's thickness. Beer's law is an approximation valid for 'weakly scattering' materials, and is given as:

I = I_0 *10^(-al), where 'a' is the *absorption coefficient* (not the same 'a' as above), and 'l' the thickness. ('t' = I/I_0)

http://en.wikipedia.org/wiki/Beer's_law

Now, you have the transmission as a percentage, but hopefully the wiki page will guide you along at this point.
 

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