Corrosion of Steel: Equilibrium & Rate Drop

In summary, when a piece of steel is placed in still water and begins to corrode, the corrosion rate will eventually decrease over time. This is because the system reaches a state of equilibrium and the layer of corrosion that forms on the steel actually protects it. In contrast, in moving water, the corrosion rate is higher because the layer of corrosion is constantly being washed away. This is similar to the process of anodizing aluminum, where the formation of aluminum oxide helps to slow down the corrosion rate.
  • #1
supasupa
24
0
Say is a piece of steel is placed in still water and is corroding. Why will the corrosion rate drop away after time??

Is it because the system reaches some sort of equlibrium??
 
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  • #2
thats ment to say : "Say if a piece of steel..." NOT " Say is a piece..."
 
  • #3
I believe the layer of corrosion protects it. Corrosion rates are higher in moving water because the corrosion covering is always being washed away.
 
  • #4
that makes sense... what you are saying is the oxide around the steel (rust) slows down the corossion rate
 
  • #5
supasupa said:
that makes sense... what you are saying is the oxide around the steel (rust) slows down the corossion rate
That is correct. This is the theory behind anodising aluminium (although aluminum oxide also exhibits excellent thermal insulation properties)
 

What is corrosion of steel?

Corrosion of steel refers to the process of the gradual destruction of steel due to chemical reactions with its environment, leading to a decrease in its strength and durability.

What factors contribute to the corrosion of steel?

The main factors that contribute to the corrosion of steel are the presence of water, oxygen, and electrolytes (such as salt), as well as the pH level and temperature of the environment.

What is the equilibrium state in the corrosion of steel?

The equilibrium state in the corrosion of steel refers to the point at which the rate of corrosion equals the rate of protection, resulting in a steady state where the steel is neither gaining nor losing mass.

What is the rate drop phenomenon in the corrosion of steel?

The rate drop phenomenon refers to the sudden decrease in the rate of corrosion that occurs after the initial stages of corrosion. This is due to the formation of protective layers on the surface of the steel that slow down the corrosion process.

How can the rate drop phenomenon be explained?

The rate drop phenomenon can be explained by the formation of passive layers on the surface of the steel, which act as a barrier against further corrosion. This can occur through the formation of oxides, carbonates, or other compounds depending on the environment.

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