Degenerate perturbation theory -- Sakurai

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Discussion Overview

The discussion revolves around the application of degenerate perturbation theory as presented in section 5.2 of "Modern Quantum Mechanics" by Sakurai and Napolitano. Participants are examining the mathematical derivations and conceptual implications of perturbation theory in quantum mechanics, particularly focusing on the treatment of degenerate energy eigenstates and the effects of perturbations on these states.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant expresses confusion regarding the derivation of an equation involving perturbation theory and the treatment of the perturbation parameter ## \lambda ##, particularly in relation to the presence of ## \lambda ## in the denominator.
  • Another participant proposes a heuristic approach to simplify the calculations by approximating the energy and suggests using a power expansion of the denominator to focus on linear terms in ## \lambda ##.
  • A different participant questions how a term of order ## \lambda^2 ## in a derived formula can yield a term of order ## \lambda ## in the resulting state, indicating a need for clarification on this point.
  • One participant, unfamiliar with the book, attempts to reason through the problem by considering the limits of the perturbation as ## \lambda ## approaches zero and suggests a method to analyze the terms involved.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the derivations and implications of the equations discussed. Multiple viewpoints and approaches are presented, indicating ongoing uncertainty and exploration of the topic.

Contextual Notes

Participants highlight limitations in their understanding of the perturbation theory calculations, particularly regarding the treatment of the perturbation parameter and the implications of terms in the derived equations. There is also a focus on the assumptions made during the derivations.

ShayanJ
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I'm reading section 5.2 "Time-Independent Perturbation Theory: The Degenerate Case" of the book "Modern Quantum Mechanics" by Sakurai and Napolitano and I have trouble with some parts of the calculations.
At firsts he explains that there is a g-dimensional subspace(which he calls D) of degenerate energy eigenstates of the unperturbed Hamiltonian which he calls ## \{|m^{0}\rangle\}##. Then he says that the perturbation will remove the degeneracy and these states will split into g states with different energies ## \{|l \rangle \} ## but if you let the perturbation parameter ## \lambda ## go to zero, you may end up with different states than ## \{|m^{0}\rangle\}##, let's call them ## \{|l^0 \rangle \} ##. Then he introduces the projection operators ## P_0 ## and ## P_1=1-P_0 ## where ## P_0 ## projects on the subspace spanned by ## \{|m^{0}\rangle\}##. Then he splits the time-independent Schrödinger equation for the ## \{|l \rangle \} ## states as below:

## 0=( E-H_0-\lambda V) |l\rangle=(E-E_D^{(0)}-\lambda V)P_0|l\rangle+( E-H_0-\lambda V)P_1 |l\rangle ##

Then he projects the above equation on the left by ## P_1 ## to get:

## -\lambda P_1 V P_0 |l\rangle+(E-H_0-\lambda P_1V)P_1|l\rangle=0 ##

Which after some manipulations, gives:

## P_1|l\rangle=P_1 \frac{\lambda}{E-H_0-\lambda P_1 V P_1}P_1 V P_0 |l\rangle ##.

Then he substitutes the expansion ## |l\rangle=|l^{(0)}\rangle+\lambda |l^{(1)}\rangle+ \dots ## into the above equation to get the equation below to order ## \lambda ##:

##\displaystyle P_1|l^{(1)}\rangle=\sum_{k \notin D} \frac{|k^{(0)} \rangle V_{kl}}{E_D^{(0)}-E_k^{(0)}} ##

But I don't understand how he got this. I just can't see what should be done!
One of the things that confuses me is that there is a ## \lambda ## in the denominator, so can we still say the order of each term just by counting the number of ## \lambda##s in the nominator? How should we account for the presence of ## \lambda ## in the denominator?

Any hint would be appreciated.
Thanks
 
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I will provide a way which I think rather heuristic because it will involve the use of approximation ##E\approx E_D^{(0)}##. Moreover, since ##\lambda## is assumed to be quite small for the perturbation method to work, the operator ##\frac{\lambda}{E-H_0-\lambda P_1 V P_1}## is approximated to be ##\frac{\lambda}{E-H_0}##. If you want, you can approach this issue from a different perspective. Consider the power expansion of the denominator of ##\frac{\lambda}{E-H_0-\lambda P_1 V P_1}## in ##\lambda##. Since we want to be working with the terms linear in ##\lambda##, one should only pick the zeroth term out of the expansion because there is already ##\lambda## in the numerator.
We will only care about the terms which contain ##\lambda##, therefore in the left hand side of
$$
P_1|l\rangle=P_1 \frac{\lambda}{E-H_0-\lambda P_1 V P_1}P_1 V P_0 |l\rangle
$$
substitute ##|l\rangle = \lambda | l^{(1)}\rangle## and in the right hand side of the above equation, substitute ##|l\rangle = |l^{(0)}\rangle## (this is so because we can be sure that the higher order terms in the expansion of ##|l\rangle## will only contribute to the terms nonlinear in ##\lambda##). Performing this step as well as incorporating the two approximations mentioned in the beginning, the above equation transforms to
$$
P_1|l^{(1)}\rangle=P_1 \frac{\lambda}{E_D^{(0)}-H_0}P_1 V P_0 |l^{(0)}\rangle
$$
The projection ##P_1## in the left most of the right hand side can be brought past ##\frac{\lambda}{E_D^{(0)}-H_0}## because they commute giving you ##P_1^2=P_1##. Using the fact that ##P_0 |l^{(0)}\rangle = |l^{(0)}\rangle## and ##P_1 = \sum_{k \notin D} |k^{(0)} \rangle \langle k^{(0)}|##, it should be pretty straightforward to see that the above equation will lead to the equation you wanted to prove.
 
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I have another equation.
After the above calculations, the formula below is derived:
## (E-E_D^{(0)}-\lambda P_0 V P_0-\lambda^2 P_0 V P_1 \frac{1}{E-H_0-\lambda V} P_1 V P_0 )P_0 |l\rangle=0 ##.

Then its said that although there is a term of order ## \lambda^2 ## in the above formula, it actually produces a term of order ## \lambda ## in the state ## P_0 |l\rangle ##. I don't understand how this is possible!
 
I don't have the book and am not familiar with these perturbation calculations but ...

Evidently when applying P0 the perturbed energy E approaches H0 quickly as λ goes to 0. So, in that fourth term, divide numerator and denominator by λ. Then ignoring the P-V-P terms the numerator becomes λ, denominator becomes (E-H0)/λ - V. As λ -> 0, (E-H0)/λ must remain finite, so overall the term is O(λ), as the book says.

I guess.
 
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