Derivation of Spin-orbit Coupling

In summary, Griffiths tries to derive the spin-orbit coupling using a classical approach, but has some trouble doing it correctly. He points out that when we choose the electron's rest frame, there is one problem as it is a non-inertial frame, so we need to consider the Thomas's precession. Finally, it cancels with the 2 we multiplied to the classically derived gyromagnetic ratio.
  • #1
kiwakwok
24
3
I was reading Griffiths's book on quantum mechanics.

In chapter 6, he tried to derive the spin-orbit coupling using a classical approach.
[tex]H=-\vec{\mu}\cdot \vec{B}[/tex]

1. Finding the relation between [itex]\vec{μ}[/itex] and [itex]\vec{S}[/itex]
He consider a spinning charged ring with mass [itex]m[/itex], radius [itex]r[/itex], total charge [itex]e[/itex] and period [itex]T[/itex].
Magnetic Dipole Moment: [itex]\vec{\mu}=i\vec{A}=\frac{e\pi r^2}{T}\hat{n}[/itex]
(Spin) Angular Momentum: [itex]\vec{S}=\tilde{I}\vec{\omega}=\frac{2m\pi r^2}{T}\hat{n}[/itex]
[tex]\vec{\mu}=\frac{e}{2m}\vec{S}[/tex]
Dirac: [itex]\frac{e}{2m}\rightarrow\frac{e}{m}[/itex]

2. Find the magnetic field [itex]\vec{b}[/itex]
He consider the rest frame of electron.
[tex]\vec{B}=\frac{\mu_0 i}{2r}\hat{n}=\frac{1}{c^2\epsilon_0}\frac{e/T}{2r}\hat{n}=\frac{1}{4\pi\epsilon_0}\frac{e}{mc^2r^3}\vec{L}[/tex]

3. Combining both terms
[tex]H=-\frac{1}{4\pi\epsilon_0}\frac{e^2}{m^2c^2r^3}\vec{L}\cdot\vec{S}[/tex]

Then he point out that when we choose the electron's rest frame, there is one problem as it is a non-inertial frame. Therefore, we need to consider the Thomas's precession, which gives a factor of 1/2. Finally, it cancels with the 2 we multiplied to the classically derived gyromagnetic ratio.


My problem is when we choose an accelerating frame, obviously we need some modifications. But, how should we modify? and how can we get the factor of 1/2 from Thomas's precession?

Thanks in advance.
 
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  • #3
kiwakwok, Unfortunately, almost all quantum books slide over the spin-orbit issue with this approach, in which quantum mechanics is temporarily abandoned, the electron is imagined to travel in a definite orbit about the nucleus, and the interaction is treated in a noninertial frame.

Doing it correctly is not at all difficult, although it involves a short calculation with the Dirac Equation. The QM book by Shiff has a good one-page derivation.
 

What is spin-orbit coupling?

Spin-orbit coupling is a phenomenon that occurs in atoms and molecules where the spin and orbital angular momentum of an electron are coupled, resulting in the splitting of energy levels.

What causes spin-orbit coupling?

Spin-orbit coupling is caused by the interaction between the electron's magnetic moment (spin) and its motion around the nucleus (orbital angular momentum). This interaction is known as the spin-orbit interaction.

Why is spin-orbit coupling important?

Spin-orbit coupling is important because it provides a way to understand and predict the behavior of atoms and molecules. It also plays a key role in many physical phenomena, such as the Zeeman effect and the fine structure of spectral lines.

How is spin-orbit coupling calculated?

The calculation of spin-orbit coupling involves solving the Schrödinger equation for the electron's wave function, taking into account the spin-orbit interaction term. This can be done using various quantum mechanical methods, such as perturbation theory or the variational method.

What are the applications of spin-orbit coupling?

Spin-orbit coupling has various applications in fields such as atomic and molecular physics, condensed matter physics, and materials science. It is also important in understanding the behavior of spintronic devices and in quantum computing.

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