Derivation of the Boltzmann distribution (Dr. David Tong)

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SUMMARY

Dr. David Tong derives the Boltzmann distribution by analyzing a system (A) in thermal contact with a heat reservoir (R) at temperature T. He presents the equation for the number of microstates of the combined system as Ω(Etotal) = ∑n ΩR(Etotal - En), where the summation is over all states of system A, each labeled as |n> with energy En. This contrasts with the misconception that the microstates of the composite system could be represented as a product of the microstates of A and R. The discussion clarifies the correct approach to understanding the multiplicity of the system.

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  • Understanding of statistical mechanics principles
  • Familiarity with microstates and macrostates
  • Knowledge of the Boltzmann distribution
  • Basic concepts of thermal equilibrium
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Students and researchers in physics, particularly those focusing on statistical mechanics and thermodynamics, will benefit from this discussion. It is also valuable for anyone seeking to deepen their understanding of the Boltzmann distribution and its derivation.

soviet1100
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Hello!

Dr. David Tong, in his statistical physics notes, derives the Boltzmann distribution in the following manner.

He considers a system (say A) in contact with a heat reservoir (say R) that is at a temperature T. He then writes that the number of microstates of the combined system (A and R) is

\Omega (E_{total}) = \sum\nolimits_{n} \Omega_{R}(E_{total}-E_n)

where the summation is over all states of the system A (states of A are labelled as |n>, each of which has energy E_n )

Can anyone help me understand how he arrives at the equation above? What about the microstates of the system A itself? I was of the understanding that the number of microstates of the composite system would be

\Omega (E_{total}) = \Omega_{R}(E_{total}-E_{n})\,. \Omega_{A}(E_{n})

Grateful for any help, thanks!
 
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I don't know the notes you are referring to, but in derivations I've seen, you take the system A to be a simple particle with a non-degenerate, discrete energy spectrum. The multiplicity of the system is then 1.
 
DrClaude said:
I don't know the notes you are referring to, but in derivations I've seen, you take the system A to be a simple particle with a non-degenerate, discrete energy spectrum. The multiplicity of the system is then 1.
thank you, DrClaude. That cleared my question.
 

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