Deriving the Boltzmann distribution

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SUMMARY

The discussion centers on the derivation of the Boltzmann distribution using the reservoir model, where the reservoir is denoted as index R and the tiny system as index A. It is established that the probability of system A being at energy e is proportional to the number of states in the reservoir, with the relationship P(e) ∝ gR. The temperature T of the entire system remains constant, leading to the conclusion that the multiplicity of states for the entire system is constant, expressed as g = gA ⋅ gR. The independence of systems A and R is crucial, as an increase in gR necessitates a decrease in gA, reinforcing the proportionality gA ∝ gR.

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  • Understanding of the Boltzmann distribution
  • Familiarity with statistical mechanics concepts
  • Knowledge of microstates and macrostates
  • Basic grasp of thermodynamic principles
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  • Study the derivation of the Boltzmann distribution in detail
  • Explore the concept of microstates and their significance in statistical mechanics
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Students and professionals in physics, particularly those focusing on statistical mechanics, thermodynamics, and the Boltzmann distribution. This discussion is beneficial for anyone seeking to deepen their understanding of energy states in systems and the relationship between microstates and macrostates.

raeed
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I was reading the derivation of Boltzmann distribution using the reservoir model.
lets call the reservoir by index R and the tiny system by index A.
In the derivation they proposed that the probability for being at energy e (for A) is proportional to the number of states in reservoir. I didn't understand this completely and i would be happy to get some help!
here is my take on it, and please correct me if I'm wrong.
- The temperature of the whole system is T and it's constant therefor the number of states for the whole systems g is also constant
- both A and R are independent of each other therefor g = gA ⋅ gR
- if gR goes up then gA has to go down meaning gA ∝ gR
- P(e) ∝ 1/gA → P(e) ∝ gR
I'm not really convinced by my explanation so if someone could explain it and perhaps give me an intuitive physical explanation, I'd be happy. Thank you
 
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The starting point is that all microstates are equally probable. Then if the system A is made up a single particle, its state has no influence on the total probability of the state of A + R (the multiplicity of A is always 1), so you can focus on the states of the reservoir only.
 

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