Determine initial and final temperatures, adiabatic expansion?

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The discussion revolves around calculating the initial and final temperatures of a diatomic gas undergoing adiabatic expansion. The user initially applied the equation PVγ = nRT but received an incorrect temperature of 159.8 K instead of the expected 394 K. Other participants pointed out that the correct approach involves using the relationship P1V1γ = P2V2γ to find the final pressure and emphasized that the equation should be PV = nRT, not PVγ = nRT. Additionally, they highlighted the importance of knowing the specific heat ratio (γ) for diatomic gases in these calculations.
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Homework Statement



A 3.25 mol sample of an ideal diatomic gas expands adiabatically from a volume of 0.1050 m^3 to 0.762 m^3. Initially the pressure was 1.00 atm

Determine the initial and final temperatures

Homework Equations



PVγ= nRT

The Attempt at a Solution



To get the initial temperature, I used the above equation

*note: converted atm to N/m^2

T = PVγ/nR = (1.013 *10^5 N/m^2)((0.1050 m^3)^1.4)/ (3.25 mol * 8.314 J/mol*K)

T = 159.8 K

Unfortunately that isn't the correct answer and the correct answer is actually 394 K. I'm pretty sure I'm going through the steps correctly. But no matter how I put the above into the calculator, I keep getting the wrong answer.

All help is appreciated! :)
 
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snowicorn said:

Homework Statement



A 3.25 mol sample of an ideal diatomic gas expands adiabatically from a volume of 0.1050 m^3 to 0.762 m^3. Initially the pressure was 1.00 atm

Determine the initial and final temperatures

Homework Equations



PVγ= nRT

The Attempt at a Solution



To get the initial temperature, I used the above equation

*note: converted atm to N/m^2

T = PVγ/nR = (1.013 *10^5 N/m^2)((0.1050 m^3)^1.4)/ (3.25 mol * 8.314 J/mol*K)

T = 159.8 K

Unfortunately that isn't the correct answer and the correct answer is actually 394 K. I'm pretty sure I'm going through the steps correctly. But no matter how I put the above into the calculator, I keep getting the wrong answer.

All help is appreciated! :)

The equation marked with red is wrong.
PV=nRT for an ideal gas. And pVγ= const during an adiabatic process.

ehild
 
snowicorn said:

Homework Statement



A 3.25 mol sample of an ideal diatomic gas expands adiabatically from a volume of 0.1050 m^3 to 0.762 m^3. Initially the pressure was 1.00 atm

Determine the initial and final temperatures

Homework Equations



PVγ= nRT

The Attempt at a Solution



To get the initial temperature, I used the above equation

*note: converted atm to N/m^2

T = PVγ/nR = (1.013 *10^5 N/m^2)((0.1050 m^3)^1.4)/ (3.25 mol * 8.314 J/mol*K)

T = 159.8 K

Unfortunately that isn't the correct answer and the correct answer is actually 394 K. I'm pretty sure I'm going through the steps correctly. But no matter how I put the above into the calculator, I keep getting the wrong answer.

All help is appreciated! :)

You should first use P1V1γ = P2V2γ to evaluate for final pressure of the gas.

And , PVγ= nRT is wrong ! Its PVγ=constant. Also it will be correct to write PV=nRT...

Hint : What is γ for diatomic gas ?
 

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