Determine initial and final temperatures, adiabatic expansion?

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SUMMARY

The discussion focuses on calculating the initial and final temperatures of a 3.25 mol sample of an ideal diatomic gas undergoing adiabatic expansion from a volume of 0.1050 m³ to 0.762 m³, with an initial pressure of 1.00 atm. The initial temperature was incorrectly calculated as 159.8 K using the equation PVγ = nRT. The correct approach involves using the adiabatic condition P1V1γ = P2V2γ to find the final pressure and then applying the ideal gas law correctly. The correct initial temperature is determined to be 394 K.

PREREQUISITES
  • Understanding of the ideal gas law (PV = nRT)
  • Knowledge of adiabatic processes and the equation P1V1γ = P2V2γ
  • Familiarity with the specific heat ratio (γ) for diatomic gases
  • Ability to convert pressure units from atm to N/m²
NEXT STEPS
  • Study the derivation and application of the adiabatic process equations
  • Learn how to calculate the specific heat ratio (γ) for various gases
  • Practice solving problems involving the ideal gas law and adiabatic processes
  • Explore the implications of adiabatic expansion on temperature and pressure changes
USEFUL FOR

Students studying thermodynamics, physics enthusiasts, and anyone looking to understand the principles of gas behavior during adiabatic processes.

snowicorn
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Homework Statement



A 3.25 mol sample of an ideal diatomic gas expands adiabatically from a volume of 0.1050 m^3 to 0.762 m^3. Initially the pressure was 1.00 atm

Determine the initial and final temperatures

Homework Equations



PVγ= nRT

The Attempt at a Solution



To get the initial temperature, I used the above equation

*note: converted atm to N/m^2

T = PVγ/nR = (1.013 *10^5 N/m^2)((0.1050 m^3)^1.4)/ (3.25 mol * 8.314 J/mol*K)

T = 159.8 K

Unfortunately that isn't the correct answer and the correct answer is actually 394 K. I'm pretty sure I'm going through the steps correctly. But no matter how I put the above into the calculator, I keep getting the wrong answer.

All help is appreciated! :)
 
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snowicorn said:

Homework Statement



A 3.25 mol sample of an ideal diatomic gas expands adiabatically from a volume of 0.1050 m^3 to 0.762 m^3. Initially the pressure was 1.00 atm

Determine the initial and final temperatures

Homework Equations



PVγ= nRT

The Attempt at a Solution



To get the initial temperature, I used the above equation

*note: converted atm to N/m^2

T = PVγ/nR = (1.013 *10^5 N/m^2)((0.1050 m^3)^1.4)/ (3.25 mol * 8.314 J/mol*K)

T = 159.8 K

Unfortunately that isn't the correct answer and the correct answer is actually 394 K. I'm pretty sure I'm going through the steps correctly. But no matter how I put the above into the calculator, I keep getting the wrong answer.

All help is appreciated! :)

The equation marked with red is wrong.
PV=nRT for an ideal gas. And pVγ= const during an adiabatic process.

ehild
 
snowicorn said:

Homework Statement



A 3.25 mol sample of an ideal diatomic gas expands adiabatically from a volume of 0.1050 m^3 to 0.762 m^3. Initially the pressure was 1.00 atm

Determine the initial and final temperatures

Homework Equations



PVγ= nRT

The Attempt at a Solution



To get the initial temperature, I used the above equation

*note: converted atm to N/m^2

T = PVγ/nR = (1.013 *10^5 N/m^2)((0.1050 m^3)^1.4)/ (3.25 mol * 8.314 J/mol*K)

T = 159.8 K

Unfortunately that isn't the correct answer and the correct answer is actually 394 K. I'm pretty sure I'm going through the steps correctly. But no matter how I put the above into the calculator, I keep getting the wrong answer.

All help is appreciated! :)

You should first use P1V1γ = P2V2γ to evaluate for final pressure of the gas.

And , PVγ= nRT is wrong ! Its PVγ=constant. Also it will be correct to write PV=nRT...

Hint : What is γ for diatomic gas ?
 

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