Differentiate between iron and copper sulphide

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SUMMARY

The discussion focuses on differentiating between iron and copper sulfide using simple chemical tests. To identify copper, dissolve the sample in hydrochloric acid (HCl) and add ammonia; a blue color indicates copper presence. If the sample does not dissolve easily, it may be an organometallic iron compound, requiring nitric acid digestion before testing. Flame tests can also be conducted after dissolving the sample, where copper will produce a green-blue flame, while iron may be less visible.

PREREQUISITES
  • Basic understanding of chemical reactions and solubility
  • Familiarity with hydrochloric acid (HCl) and nitric acid (HNO3)
  • Knowledge of flame test procedures
  • Safety protocols for handling acids
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  • Research the properties and reactions of organometallic iron compounds
  • Learn about safe handling and disposal of hydrochloric and nitric acids
  • Explore advanced techniques for metal identification in unknown samples
  • Study the principles of flame tests and their applications in chemistry
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This discussion is beneficial for amateur chemists, hobbyists in material identification, and anyone interested in basic chemical testing methods for metals.

Jehannum
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TL;DR
Simple chemical / flame test needed to identify substance
I have a quantity of black, lustrous powder taken from inside a gas pipe.

I want to know whether it's from copper pipe or from steel pipe.

Is there a very simple test I can do? I'm not a chemist and have no specialist equipment.
 
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Dissolve it in HCL. To several drops of the liquid add several drops of ammonia. If it turns blue, it contains copper. If it forms a ppt, it’s iron.

If it won’t dissolve easily, it is probably an organometallic iron compound or an iron compound with organic “stuff” coating it. In that case you would need to digest the sample with nitric acid before adding the ammonia. You need special equipment and protections to handle that.
If you want to do flame tests, you need to dissolve some of it first... either with HCl or HNO3 (nitric acid). Dissolve the sample, decant or filter and heat to boil. Reduce to a moist solid and reconstitute in a minimum of DI water. Dip a q-tip into the liquid and hold over a BLUE flame to observe the color. Iron will likely be difficult to see but copper (green-blue) is easy.
 
To amplify @chemisttree nice post:

HCl is hydrochloric acid, which you can get at hardware and pool supply stores.
 

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