B Do eigenstate probabilities change with time?

Click For Summary
Quantum systems can be expressed as linear combinations of eigenstates of Hermitian operators, with eigenvalues representing observable properties. The time evolution of these states is governed by the time-dependent Schrödinger equation, which indicates that the weights of different eigenstates can change over time, particularly in systems like Gaussian wave functions in free space. Energy eigenstates are stationary states, meaning their observable expectation values remain constant over time, while superpositions of energy eigenstates exhibit time-dependent expectation values. For observables that commute with the Hamiltonian, their expectation values do not change, but for others, they may vary. If the Hamiltonian is time-dependent, all observables will generally also change over time.
sgphysics
Messages
20
Reaction score
2
To my understanding any quantum system can be describes as a linear combination of eigenstates or eigevectors of any hermetian operator, and that the eigen values represent the observable properties. But how does the system change with time? I suppose big systems with many particles change with time. Do the weights for the different eigenstates change with time?
 
Physics news on Phys.org
We have time dependent Shrodinger equation to describe time evolution of the states. For an example in diffusion of Gaussian wave function in free space, weights of different position eigenstates change with time.
 
Last edited:
sgphysics said:
To my understanding any quantum system can be describes as a linear combination of eigenstates or eigevectors of any hermetian operator, and that the eigen values represent the observable properties. But how does the system change with time? I suppose big systems with many particles change with time. Do the weights for the different eigenstates change with time?
An energy eigenstate is also called a stationary state because the expectation value of all observables is independent of time. This is not the case for a superposition of energy eigenstates.

The expectation value of any observable whose operator commutes with the Hamiltonian does not change over time. For other observables the expectation value may be time dependent, as above.

E.g. if you have the quantum harmonic oscillator in a superposition of energy eigenstates, then the expectation values of position and momentum change harmonically over time.

PS this assumes a time independent Hamiltonian. If the Hamiltonian itself depends on time then in general so do all observables.
 
For the quantum state ##|l,m\rangle= |2,0\rangle## the z-component of angular momentum is zero and ##|L^2|=6 \hbar^2##. According to uncertainty it is impossible to determine the values of ##L_x, L_y, L_z## simultaneously. However, we know that ##L_x## and ## L_y##, like ##L_z##, get the values ##(-2,-1,0,1,2) \hbar##. In other words, for the state ##|2,0\rangle## we have ##\vec{L}=(L_x, L_y,0)## with ##L_x## and ## L_y## one of the values ##(-2,-1,0,1,2) \hbar##. But none of these...