Nernst equation is what describes the voltage when you refer to the chemistry only.
For the reaction
Redm <-> Ox(m+n) + ne
cell potential is
[tex]E = E_0 + \frac {RT}{nF} \ln \frac{a_{Ox}}{a_{Red}}[/tex]
where F is a Faraday constant, aOx and aRed are activities of the reduced and oxidized form. Expression under the logarithm may take more complicated form for more complicated reactions. Besides, there are always two reactions taking place, and the observed potential is a difference between potentials of both half cells, but the total voltage will be still described by the Nernst equation, just the ln part will change. Activities change almost linearly with the charge level.