Does quantization always work?

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  • #101
my2cts said:
"Does quantization always work?"
My answer to the original question is yes, as quantum physics always works.
If quantization does not work the applied procedure is wrong, incorrectly executed, or both.
Then the discussion went on about tensor products of Hilbert spaces.
I wonder what is the consequence of this for a simple physical system such as the hydrogen atom.
If there is none, as I believe, the math must be wrong or incorrectly applied.
The specific question was about the hydrogen atom Hilbert space. That has been answered:##\mathcal{H}_{Com}\otimes \mathcal{H}_{rel}=L^2(R^6)## that avoids the problem with the potential mentioned by dextercioby.
Where do you see wrong or incorrectly applied math here?
 
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  • #103
TrickyDicky said:
The specific question was about the hydrogen atom Hilbert space. That has been answered:##\mathcal{H}_{Com}\otimes \mathcal{H}_{rel}=L^2(R^6)## that avoids the problem with the potential mentioned by dextercioby.
Where do you see wrong or incorrectly applied math here?
My comment is intended to provoke a physically more clear statement of the issue.
Concerning the Hilbert space of H, ##\mathcal{H}_{p}\otimes \mathcal{H}_{e}=L^2(R^6)## also does the job.
 
  • #104
bhobba said:
That depends on what you mean by 'work'. In QM there is an operator order issue:
http://motls.blogspot.com.au/2012/12/ordering-ambiguities-and.html
Bill
It also depends on what is meant by quantization. In any case, the hydrogen problem poses no problems.
Thus, if there is a mathematical problem it must be the math not the atom ;-).
 
  • #105
dextercioby said:
I'm still having a trouble to understand why those projectors can be used in a tensor product decomposition, since the |x_e\rangle\ from that product is not even known, not to mention that the (possibly rigged) Hilbert space in which it "lives" is also not known.
Isn't it? One can take the (generalized) momentum eigenstates for a free electron, giving a rigged Hilbert space expressed in momentum basis. Then perform a Fourier transform...
 

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