Effect of temperature on voltage

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Discussion Overview

The discussion centers on the effect of temperature on voltage, specifically in the context of silicon solar cells. Participants are exploring the reasons behind the decrease in open circuit voltage with rising temperature, seeking explanations and insights.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant notes a general understanding that voltage decreases with temperature but seeks a deeper explanation.
  • Another participant suggests that increased temperature raises the kinetic energy of electrons, leading to more frequent scattering events with the lattice, which may decrease current and thus voltage, though they express uncertainty about this reasoning.
  • A third participant references an external source for further discussion on the topic.
  • A fourth participant mentions a related concept regarding the knee voltage of diodes decreasing with temperature, implying a connection but not elaborating further.

Areas of Agreement / Disagreement

Participants generally agree that voltage decreases with temperature, but the underlying reasons remain contested and not fully resolved, with differing explanations and levels of certainty expressed.

Contextual Notes

Some assumptions about the relationship between temperature, electron behavior, and voltage are not fully articulated, and the discussion does not resolve the mathematical or physical principles involved.

vw_g60t
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Hi,

I know that voltage decreases with temperature but why?

I am looking into silicon solar cells but cannot find any sources which explain why open circuit voltage decreases with rise in temperature.

can some explain please!

thanks
 
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vw_g60t said:
Hi,

I know that voltage decreases with temperature but why?

I am looking into silicon solar cells but cannot find any sources which explain why open circuit voltage decreases with rise in temperature.

can some explain please!

thanks

I cannot give you a rigorous explanation, but I think (but I'm not totally sure) that the increase of temperature causes the increase of the electrons' kinetic energy. That's why the scattering events between electrons and the lattice occur more frequently: this fact decrease the current, and so the voltage.
 
Please refer to my contribution in another discussion. The knee voltage of the diode decreases with temperature.
 

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