Einstein's theory for specific heat

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SUMMARY

The discussion centers on Einstein's theory of specific heat, specifically the formula for average energy per vibrational mode given by $$\frac{h\nu}{e^{\frac{h\nu}{T}}-1$$. It is established that the total internal energy, U, is calculated as $$U=(\text{number of vibrational modes)}\times\frac{h\nu}{e^{\frac{h\nu}{T}}-1$$, with the number of vibrational modes being 3N for a monoatomic structure. The discussion highlights that Einstein's model does not account for rotational degrees of freedom and emphasizes that at room temperature, the specific heat of solids is primarily influenced by lattice vibrations, aligning with more advanced models like Debye's.

PREREQUISITES
  • Understanding of quantum mechanics concepts, particularly energy quantization.
  • Familiarity with statistical mechanics and thermodynamic principles.
  • Knowledge of solid-state physics, specifically vibrational modes in crystals.
  • Basic comprehension of Einstein's model of specific heat and its limitations.
NEXT STEPS
  • Explore Debye's model of specific heat and its advantages over Einstein's model.
  • Study the role of lattice vibrations in determining thermal properties of solids.
  • Investigate the mathematical derivation of specific heat equations in solid-state physics.
  • Learn about the experimental methods used to measure specific heat in materials.
USEFUL FOR

Students and researchers in physics, particularly those focused on thermodynamics, solid-state physics, and materials science, will benefit from this discussion.

Titan97
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I have uploaded a page from my prof's lecture on specific heat.

Its given that average energy for each vibrational mode is $$\frac{h\nu}{e^{\frac{h\nu}{T}}-1}$$

Hence $$U=(\text{number of vibrational modes)}\times\frac{h\nu}{e^{\frac{h\nu}{T}}-1}$$

In the lecture slide, the number of vibrational mode is 3N. Is this for a monoatomic structure? Because it doesn't consider rotational degree of freedom.
 

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There is no rotational mode in Einstein's model.
He models the crystal as a collection of uncoupled harmonic oscillators, all oscillating with the same frequency.

And if we switch to more realistic models like Debye's or to experimental results, the specific heat of solids around room temperature is due to lattice vibrations only.
 
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