How Do You Write Electron Configurations for Ions?

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To write electron configurations for ions, adjust the last subshell based on the ion's charge: add an electron for negative ions and subtract one for positive ions. For example, sodium (Na) has the configuration [Ne] 3s1; Na- becomes [Ne] 3s2, while Na+ is just [Ne]. Chlorine (Cl) has the configuration [Ne] 3s2 3p5; Cl- is [Ar], and Cl+ is [Ne] 3s2 3p4. Special care is needed for transition metals, such as titanium (Ti), where the configuration [Ar] 4s2 3d2 changes to [Ar] 4s1 3d2 for Ti+. The key is to remove electrons from the highest energy orbitals first.
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How would I write the configuration for ions? Would I alter the last subshell (e.g. 1s2 2s2 2p6 3s2 3p6 4s2 3d10: I change 3d10) or the shell with the n and l (1s2 2s2 2p6 3s2 3p6 4s2 3d10: I change 4s2)? Thanks.
 
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If your ion has a negative charge, add one electron to the electron configuration. If your ion is positive, subtract one electron.

For example, take Na. The electron configuration for the atom is [Ne] 3s1. If you have Na- it becomes [Ne] 3s2 & Na+, just [Ne].
Another example, suppose you have Cl, the electron configuration is [Ne] 3s2 3p5. Cl- is [Ar] & Cl+ is [Ne] 3s2 3p4. Notice how you add & subtract from the orbital with the highest energy

You have to be careful with the transition metals. Take for example Ti, its electron configuration is [Ar] 4s2 3d2. Ti- is [Ar] 4s2 3d3. But here is where it "can" be tricky. Ti+ is [Ar] 4s1 3d2. The d orbitals are written after the s, but the 4s orbitals are still of higher energy. So you remove from them first, before the d orbitals.
 
kuahji said:
If your ion has a negative charge, add one electron to the electron configuration. If your ion is positive, subtract one electron.

For example, take Na. The electron configuration for the atom is [Ne] 3s1. If you have Na- it becomes [Ne] 3s2 & Na+, just [Ne].
Another example, suppose you have Cl, the electron configuration is [Ne] 3s2 3p5. Cl- is [Ar] & Cl+ is [Ne] 3s2 3p4. Notice how you add & subtract from the orbital with the highest energy

You have to be careful with the transition metals. Take for example [B]Ti, its electron configuration is [Ar] 4s2 3d2. Ti- is [Ar] 4s2 3d3. But here is where it "can" be tricky. Ti+ is [Ar] 4s1 3d2. [/B] The d orbitals are written after the s, but the 4s orbitals are still of higher energy. So you remove from them first, before the d orbitals.

This tricky was on our test last week and...I totally lost lol.
 

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