Here's another proof:
Say you have 4 unit-area plates stacked close together vertically. 4 plates, numbered 1 to 4, left to right. 3 gaps.
Number the surfaces 1 thru 8 left to right.
Put charge Q on plate 1 and -Q on plate 4. Assume the center two plates have zero charge.
Fact: the charges on each facing pair of surfaces (e.g. #2 & #3 or #4 & #5) must be equal and opposite, otherwise the divergence in the E field is non-zero which violates Maxwell.
Thus,
## \sigma_2 = \sigma_4 = \sigma_6 = -\sigma_3 =- \sigma_5 = -\sigma_7 ##.
But also, ## \sigma_1 + \sigma_2 = Q ## and
## \sigma_7 + \sigma_8 = -\sigma_2 + \sigma_8 = -Q ##.
Now put a + test charge inside plate 1. This charge will see a rightward force due to ## \sigma_1 ## and a leftward force force due to ## \sigma_8 ##. Note that ## \sigma_2 ## thru ## \sigma_7 ## forces cancel each other out.
That leaves us with
## \sigma_1 + \sigma_2 = Q ##
## \sigma_8 - \sigma_2 = -Q ##
and since the net force on the test charge must = 0,
## \sigma_1 - \sigma_8 = 0 ##.
OK look at these equations. They have no solution!
So the assumed charge distribution is impossible.
Matter of fact, no matter what charge you put on each plate, no matter how many plates, the outside 2 surfaces must have the same charge including sign!