Energy bands diagram in semiconductors

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SUMMARY

The discussion centers on the significance of the wave vector "k" in the context of energy band diagrams for semiconductors. The wave vector "k" represents the reciprocal of the space wavelength and is crucial for understanding the momentum of particles in a lattice structure. In free space, momentum is a well-defined quantum number, but in a lattice, it becomes periodic due to the constraints of lattice vectors. This periodicity is essential for accurately plotting energy versus k in semiconductor physics.

PREREQUISITES
  • Understanding of wave vectors in quantum mechanics
  • Familiarity with energy band theory in solid-state physics
  • Knowledge of lattice structures and periodicity
  • Basic concepts of momentum in quantum systems
NEXT STEPS
  • Research the concept of reciprocal lattice vectors in solid-state physics
  • Study the implications of Bloch's theorem on energy bands
  • Learn about the relationship between k-space and electronic properties of semiconductors
  • Explore the mathematical formulation of energy band diagrams
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Students and professionals in physics, particularly those specializing in semiconductor physics, materials science, and solid-state electronics will benefit from this discussion.

mendes
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We usually plot the energy versus k, the wave vector, in the so-called "energy band diagram" for semiconductors. I am trying to understand the significance of "k" in this case. k is the wave vector, which means come kind of reciprocal of the space wavelength of the wave. But this definition does not make me understand the utility of plotting the energy versus k ! Does k mean something else also ?
 
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\hbar k is the momentum, modulo crystal momentum.

In free space, symmetry under translations mean that momentum is a good quantum number (i.e. it makes sense to label energy eigenstates with it). In a lattice, you can only translate by lattice vectors; mathematically, you have something like momentum, but is periodic instead.
 

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