Entropy change when the number of particles decreases

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SUMMARY

The discussion centers on the calculation of entropy change when the number of particles decreases from ##N_1## to ##N_2=N_1/2##. The established solution indicates that the entropy decreases by $$\Delta S=-k\cdot N_1\cdot \ln{2}$$. The participant expresses confusion regarding the argument, particularly the assumption of non-interacting particles and the lack of knowledge about the number of microstates ##\Omega##. They argue that in a chemical reaction within an isolated container, the system's entropy would increase rather than decrease, challenging the exercise's validity.

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greypilgrim
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Hi.

I found following exercise in a high school textbook:
"Compute the entropy change in following process:"
SCAN0015.png

The solution is
"The number of particles decreases from ##N_1## to ##N_2=N_1/2##. Hence the entropy decreases by
$$\Delta S=-k\cdot N_1\cdot \ln{2}\enspace ."$$

I can't quite follow the argument here. Assuming the particles in each picture are non-interacting and have the same number of microstates ##\Omega##, I get
$$S_1=N_1\cdot k\cdot \ln{\Omega}$$
$$S_2=N_2\cdot k\cdot \ln{\Omega}=\frac{N_1}{2}\cdot k\cdot \ln{\Omega}=\frac{S_1}{2}$$
from which I can see that the entropy decreases, but cannot compute the difference since I don't know ##\Omega##.
 
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I have doubts that the exercise makes much sense. E.g. if this is meant to be a chemical reaction in an isolated container, the system will heat up and entropy will increase rather than decrease.
 

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