It does not matter in this case because the first row of Inv(T) equals the first column.
Anyway, I much prefer to avoid matrix inverses altogether. What you have is an equation-solving problem, and using a matrix inverse is one of the worst ways to do it (although is often used nevertheless). If your 4x4 matrix T has first row [-2r,r,0,0] and last row [0,0,r,-2r], the equations you need to solve for the ruin probabilities ##u_1,u_2,u_3,u_4## are:
$$\begin{array}{rcl}
0 = r - 2r u_1 + r u_2 &\Rightarrow& u_1 = \frac{1}{2} + \frac{1}{2} u_2 \\
0 = r u_1 - 2r u_2 + u_3 &\Rightarrow& u_2 = \frac{1}{2} u_1 + \frac{1}{2} u_3 \\
0 = r u_2 -2r u_3 + r u_4 &\Rightarrow&u_3 = \frac{1}{2} u_2 + \frac{1}{2} u_4 \\
0 = r u_3 - 2r u_4 & \Rightarrow& u_4 = \frac{1}{2} u_3
\end{array}
$$
That's it: just solve those equations. You will get ##(u_1,u_2,u_3,u_4) = (4/5, \, 3/5, \, 2/5, \, 1/5)## for any ##r > 0##.